Synthesis, characterization and theoretical calculations of ZnTiO3 for the adsorption and photocatalytic removal of Methylene Blue dye

Identificador:  TDX:3865

Handle: https://hdl.handle.net/20.500.11797/TDX3865

Autors:  Jaramillo Fierro, Ximena Verónica

Resum:
Currently, nanomaterials have aroused great interest for environmental applications, such as the removal of colorants in wastewater. The purpose of this thesis was the preparation of structured materials with adsorbent and photocatalytic properties for the removal of the cationic methylene blue (MB) dye in aqueous solutions. To do this, initially, several Ecuadorian clays were collected and characterized, which were used as supports for photocatalysts prepared based on zinc and titanium. The photocatalysts ZnTiO3/TiO2, ZnTiO3/TiO2/La and TiO2 (anatase phase) were synthesized by the sol-gel method. G-Clay and R-Clay clays were used as raw material sources to synthesize FAU and LTA zeolites, respectively, by alkaline fusion and hydrothermal method. The zeolites were combined with their precursor clays and with the photocatalysts to prepare pellets that were successfully used in MB removal tests in aqueous solutions. The experimental isotherms were adjusted to the Langmuir model and the experimental kinetics to the pseudo-second-order model, which showed monolayer adsorption on a surface that contained an infinite number of identical sites, maintaining a constant adsorption rate during the process