Repositori URV

Identificador: TDX:780

Handle: https://hdl.handle.net/20.500.11797/TDX780

Autors:
Mercado Roca, Luis Adolfo

Resum:
The epoxy resins are widely used in coatings, adhesives, composites, etc. In some applications of epoxy resins special and versatile features are required, such as high adhesion to the substrates, low shrinkage, low thermal stress after curing, toughness, chemical resistance and low flammability. The flammability of epoxy resins is the main drawback in their application. Some flame retardants compounds, such as brominebased compounds, antimony oxides, phosphorous-halogen compounds etc. are incorporated in the epoxy resins to reduce their flammability. These compounds are exceptionally efficient but they have the inconvenience that they increase the smoke and toxic and corrosive gas evolution during the combustion of the polymer. For these drawbacks in the last years it has been increased the investigation of other heteroatoms like flame retardants to replace the halogens.Some approaches about epoxy resins with silicon covalently bonded to the polymeric matrix have been reported. In this way, modifications of commercial epoxy resins and copolymerizations of silicon-based monomers with commercial epoxy resins giving to good flame retardancy, thermal and mechanical properties have been reported.The aim of this thesis is the development of novel fire retardant silicon-based epoxy resins. Glycidyl monomers with silicon in their structure, prepolymers obtained by mean of growth of chain reactions between diphenyl silanediol and diglycidylether of bisphenol A (DGEBA) and a phosphorous-containing glycidyl monomer and two phosphorilated diamines were synthesized. Thermoset polymers were obtained from curing reactions of the compounds synthesized. To study the reaction kinetics of silicon-containing epoxy monomer with primary amines, a monofunctional silicon-containing epoxy mono