Tesis doctorals> Departament de Química

Design, synthesis and binding studies of calix(4)pyrrole based receptors suitable for ion-pair complexation and n-oxide recognition. Synthesis of resorcin(4) arene derivatives as potential ligands for supramolecular catalysis

  • Identification data

    Identifier: TDX:1114
    Handle: https://hdl.handle.net/20.500.11797/TDX1114
    Authors:
    Ciardi, Moira
    Abstract:
    The work developed during the PhD thesis deals mainly with the design and synthesis ofSupramolecular Hosts. In particular, we present new aryl-extended calix[4]pyrroleswith two or four phosphonate groups as heteroditopic receptors for the complexation of ion-pairs and that result important for the extraction of salts and for the transportof ions through membranes. Likewise, derivativesofcalix[4]pyrroles have been prepared for the selective inclusionofN-oxides in high energy conformation.The importance of the inclusion has been demonstrated by the change of the reactivity of the N-oxide in reactions in which it is commonly used as co-catalyst. Finally, we present derivatives ofresorcin[4]arenes with ethyl groups at the lower rim of thereceptor and a mobile wall in the upper rim as potential ligands for Supramolecular catalysis.

  • Others:

    Date: 2012-10-11
    Departament/Institute: Departament de Química Analítica i Química Orgànica Universitat Rovira i Virgili.
    Language: eng
    Identifier: http://hdl.handle.net/10803/90244
    Source: TDX (Tesis Doctorals en Xarxa)
    Author: Ciardi, Moira
    Director: Ballester Balaguer, Pablo
    Format: application/pdf 226 p.
    Publisher: Universitat Rovira i Virgili
    Keywords: Ligandos supramoleculares N-Oxido Receptores de pares iónicos
    Title: Design, synthesis and binding studies of calix(4)pyrrole based receptors suitable for ion-pair complexation and n-oxide recognition. Synthesis of resorcin(4) arene derivatives as potential ligands for supramolecular catalysis
    Subject: 547 - Química orgànica 544 - Química física 54 - Química

  • Keywords:

    547 - Química orgànica
    544 - Química física
    54 - Química

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