Hetero-michael addition to sunflower oil derivatives as precusors of polymeric materials

Identifier:  TDX:1296

Handle: https://hdl.handle.net/20.500.11797/TDX1296

Authors:  Moreno Rueda, Maryluz

Abstract:
Abstract The principal objective of this thesis is the synthesis of polymeric materials from vegetable oils derivatives. In the first step different flame retardant thermosetting polymers were synthesized through chemical modifications of commercial high oleic sunflower oil followed byaddition and crosslinking via phospha and aza-Michael addition. In the second step lineal polyesters and thermosets were synthesis through thiol-Michael addition to sunflower oil derivatives. The lineal polyesters were modified to wide their biology or biomedical applications. Furthermore the development a novel nanocomposite with cellulose nanocrystal material was carrie out. As general conclusion polymers from vegetables oil derivatives were development successfully