Treballs Fi de MàsterEnginyeria Química

OBTAINING HIGH-VALUE ADDED PRODUCTS FROM CELLULOSE: IMPACT OF CELLULOSE TREATMENT WITH HYDROTALCITES IN HYDROTHERMAL CATALYTIC CONVERSION

  • Identification data

    Identifier:  TFM:179
    Authors:  Guarín Villegas, Carlos Andres
    Abstract:
    The development of platform chemicals from biomass arises as an alternative for the sustainable progress of the chemical industry. With this in mind, the conversion of cellulose to value added products such as lactic acid using hydrotalcites (HT) as catalyst was investigated. Mg-Al hydrotalcites were used as catalyst for the hydrolysis of cellulose into lactic, acetic, formic and glycolic acids. Catalysts were characterized by XRD, FTIR, ESEM and BET surface area analysis. The best conversion yield of up to 30% with selectivity was obtained over calcined hydrotalcites at 400°C after being synthesized in aqueous medium at pH 10. Finally, a reaction route is proposed to illustrate the cellulose transformation.
  • Others:

    Entity: Universitat Rovira i Virgili (URV)
    Confidenciality: No
    Education area(s): Nanociència, Materials i Processos - Tecnologia Química de Frontera 
    Subject: Enginyeria química
    Academic year: 2015-2016
    Work's public defense date: 2016-09-08
    Student: Guarín Villegas, Carlos Andres
    Work's codirector: Constantí Garriga, Magdalena
    Department: Enginyeria Química
    Creation date in repository: 2017-01-13
    TFM credits: 24
    Access Rights: info:eu-repo/semantics/openAccess
    Project director: Medina Cabello, Francisco
  • Keywords:

    Cellulose
    hydrotalcites
    catalytic conversion
    Chemical engineering
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