Autor segons l'article: Lligadas, G.; Grama, S.; Percec, V.
Departament: Química Analítica i Química Orgànica
Autor/s de la URV: LLIGADAS PUIG, GERARD; Grama, S.; Percec, V.
Paraules clau: Monomers Living polymerization Electron transitions
Resum: Single electron transfer-living radical polymerization (SET-LRP) represents a robust and versatile tool for the synthesis of vinyl polymers with well-defined topology and chain end functionality. The crucial step in SET-LRP is the disproportionation of the Cu(I)X generated by activation with Cu(0) wire, powder, or nascent Cu(0) generated in situ into nascent, extremely reactive Cu(0) atoms and nanoparticles and Cu(II)X2. Nascent Cu(0) activates the initiator and dormant chains via a homogeneous or heterogeneous outer-sphere single-electron transfer mechanism (SET-LRP). SET-LRP provides an ultrafast polymerization of a plethora of monomers (e.g., (meth)-acrylates, (meth)-acrylamides, styrene, and vinyl chloride) including hydrophobic and water insoluble to hydrophilic and water soluble. Some advantageous features of SET-LRP are (i) the use of Cu(0) wire or powder as readily available catalysts under mild reaction conditions, (ii) their excellent control over molecular weight evolution and distribution as well as polymer chain ends, (iii) their high functional group tolerance allowing the polymerization of commercial-grade monomers, and (iv) the limited purification required for the resulting polymers. In this Perspective, we highlight the recent advancements of SET-LRP in the synthesis of biomacromolecules and of their conjugates.
Grup de recerca: Polimers Sostenibles
Àrees temàtiques: Chemistry Química Química
Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 1525-7797
Identificador de l'autor: ; ;
Data d'alta del registre: 2017-05-04
Pàgina final: 1063
Volum de revista: 18
Versió de l'article dipositat: info:eu-repo/semantics/publishedVersion
Enllaç font original: http://pubs.acs.org/doi/abs/10.1021/acs.biomac.7b00197
URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
DOI de l'article: 10.1021/acs.biomac.7b00197
Entitat: Universitat Rovira i Virgili
Any de publicació de la revista: 2017
Pàgina inicial: 1039
Tipus de publicació: Article Artículo Article
Repositori URV