Autor según el artículo: Lligadas, G.; Grama, S.; Percec, V.
Departamento: Química Analítica i Química Orgànica
Autor/es de la URV: LLIGADAS PUIG, GERARD; Grama, S.; Percec, V.
Palabras clave: Monomers Living polymerization Electron transitions
Resumen: Single electron transfer-living radical polymerization (SET-LRP) represents a robust and versatile tool for the synthesis of vinyl polymers with well-defined topology and chain end functionality. The crucial step in SET-LRP is the disproportionation of the Cu(I)X generated by activation with Cu(0) wire, powder, or nascent Cu(0) generated in situ into nascent, extremely reactive Cu(0) atoms and nanoparticles and Cu(II)X2. Nascent Cu(0) activates the initiator and dormant chains via a homogeneous or heterogeneous outer-sphere single-electron transfer mechanism (SET-LRP). SET-LRP provides an ultrafast polymerization of a plethora of monomers (e.g., (meth)-acrylates, (meth)-acrylamides, styrene, and vinyl chloride) including hydrophobic and water insoluble to hydrophilic and water soluble. Some advantageous features of SET-LRP are (i) the use of Cu(0) wire or powder as readily available catalysts under mild reaction conditions, (ii) their excellent control over molecular weight evolution and distribution as well as polymer chain ends, (iii) their high functional group tolerance allowing the polymerization of commercial-grade monomers, and (iv) the limited purification required for the resulting polymers. In this Perspective, we highlight the recent advancements of SET-LRP in the synthesis of biomacromolecules and of their conjugates.
Grupo de investigación: Polimers Sostenibles
Áreas temáticas: Chemistry Química Química
Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 1525-7797
Identificador del autor: ; ;
Fecha de alta del registro: 2017-05-04
Página final: 1063
Volumen de revista: 18
Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
Enlace a la fuente original: http://pubs.acs.org/doi/abs/10.1021/acs.biomac.7b00197
URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
DOI del artículo: 10.1021/acs.biomac.7b00197
Entidad: Universitat Rovira i Virgili
Año de publicación de la revista: 2017
Página inicial: 1039
Tipo de publicación: Article Artículo Article
Repositori URV