Autor segons l'article: Smirnova, Ekaterina S; Munoz Molina, Jose M; Johnson, Alice; Bandeira, Nuno A G; Bo, Carles; Echavarren, Antonio M
Departament: Química Física i Inorgànica
Autor/s de la URV: Bo Jané, Carles / ECHAVARREN PABLOS, ANTONIO
Paraules clau: Ureas; Urea; Synthesis (chemical); Structure elucidation; Silver halides; Primary amines; Phosphine-ligands; Palladium; Or; Nanoparticles; Nanoclusters; Mild reaction conditions; Homogeneous conditions; Homogeneous catalysis; Heterometallic complexes; Gold nanoparticles; Gold compounds; Gold; Crystal-structure; Clusters; Chemistry; Catalyzed oxidative carbonylation; Catalysis; Catàlisi homogènia; Carbonylation; Carbonyl compounds; Carbonilació; C-h functionalization; Bond; Amines; homogeneous catalysis; heterometallic complexes; gold; carbonylation
Resum: The synthesis of tetranuclear gold complexes, a structurally unprecedented octanuclear complex with a planar [Au(I) 8 ] core, and pentanuclear [Au(I) 4 M(I) ] (M=Cu, Ag) complexes is presented. The linear [Au(I) 4 ] complex undergoes C-H functionalization of carbonyl compounds under mild reaction conditions. In addition, [Au(I) 4 Ag(I) ] catalyzes the carbonylation of primary amines to form ureas under homogeneous conditions with efficiencies higher than those achieved by gold nanoparticles.© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Àrees temàtiques: Química; Medicina ii; Medicina i; Materiais; Interdisciplinar; General medicine; General chemistry; Farmacia; Engenharias ii; Ciências biológicas iii; Ciências biológicas ii; Ciências biológicas i; Chemistry, multidisciplinary; Chemistry (miscellaneous); Chemistry (all); Chemistry; Catalysis; Astronomia / física
Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
Adreça de correu electrònic de l'autor: carles.bo@urv.cat; antoniomaria.echavarren@urv.cat
Data d'alta del registre: 2025-02-19
Versió de l'article dipositat: info:eu-repo/semantics/publishedVersion
Enllaç font original: https://onlinelibrary.wiley.com/doi/10.1002/anie.201603200
URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
Referència a l'article segons font original: Angewandte Chemie (International Ed. Print). 55 (26): 7487-7491
Referència de l'ítem segons les normes APA: Smirnova, Ekaterina S; Munoz Molina, Jose M; Johnson, Alice; Bandeira, Nuno A G; Bo, Carles; Echavarren, Antonio M (2016). Polynuclear Gold [AuI]4, [AuI]8, and Bimetallic [AuI 4AgI] Complexes: C-H Functionalization of Carbonyl Compounds and Homogeneous Carbonylation of Amines. Angewandte Chemie (International Ed. Print), 55(26), 7487-7491. DOI: 10.1002/anie.201603200
DOI de l'article: 10.1002/anie.201603200
Entitat: Universitat Rovira i Virgili
Any de publicació de la revista: 2016
Tipus de publicació: Journal Publications
Repositori URV