Articles producció científicaQuímica Física i Inorgànica

Polynuclear Gold [AuI]4, [AuI]8, and Bimetallic [AuI 4AgI] Complexes: C-H Functionalization of Carbonyl Compounds and Homogeneous Carbonylation of Amines

  • Identification data

    Identifier:  imarina:2107528
    Handle: https://hdl.handle.net/20.500.11797/imarina2107528
    Authors:  Smirnova, ES; Molina, JMM; Johnson, A; Bandeira, NAG; Bo, C; Echavarren, AM
    Abstract:
    The synthesis of tetranuclear gold complexes, a structurally unprecedented octanuclear complex with a planar [Au(I) 8 ] core, and pentanuclear [Au(I) 4 M(I) ] (M=Cu, Ag) complexes is presented. The linear [Au(I) 4 ] complex undergoes C-H functionalization of carbonyl compounds under mild reaction conditions. In addition, [Au(I) 4 Ag(I) ] catalyzes the carbonylation of primary amines to form ureas under homogeneous conditions with efficiencies higher than those achieved by gold nanoparticles.© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  • Others:

    Link to the original source: https://onlinelibrary.wiley.com/doi/10.1002/anie.201603200
    APA: Smirnova, ES; Molina, JMM; Johnson, A; Bandeira, NAG; Bo, C; Echavarren, AM (2016). Polynuclear Gold [AuI]4, [AuI]8, and Bimetallic [AuI 4AgI] Complexes: C-H Functionalization of Carbonyl Compounds and Homogeneous Carbonylation of Amines. Angewandte Chemie (International Ed. Print), 55(26), 7487-7491. DOI: 10.1002/anie.201603200
    Paper original source: Angewandte Chemie (International Ed. Print). 55 (26): 7487-7491
    Article's DOI: 10.1002/anie.201603200
    Journal publication year: 2016-06-20
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/publishedVersion
    Record's date: 2026-05-09
    URV's Author/s: Bo Jané, Carles / ECHAVARREN PABLOS, ANTONIO
    Department: Química Física i Inorgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Journal Publications
    Author, as appears in the article.: Smirnova, ES; Molina, JMM; Johnson, A; Bandeira, NAG; Bo, C; Echavarren, AM
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Thematic Areas: General medicine, General chemistry, Chemistry, multidisciplinary, Chemistry (miscellaneous), Chemistry (all), Chemistry, Catalysis, Astronomia / física
    Author's mail: carles.bo@urv.cat, carles.bo@urv.cat, antoniomaria.echavarren@urv.cat, antoniomaria.echavarren@urv.cat

  • Keywords:

    Ureas
    Urea
    Synthesis (chemical)
    Structure elucidation
    Silver halides
    Primary amines
    Phosphine-ligands
    Palladium
    Or
    Nanoparticles
    Nanoclusters
    Mild reaction conditions
    Homogeneous conditions
    Homogeneous catalysis
    Heterometallic complexes
    Gold nanoparticles
    Gold compounds
    Gold
    Crystal-structure
    Clusters
    Chemistry
    Catalyzed oxidative carbonylation
    Catalysis
    Catàlisi homogènia
    Carbonylation
    Carbonyl compounds
    Carbonilació
    C-h functionalization
    Bond
    Amines
    Chemistry (Miscellaneous)
    Multidisciplinary
    General medicine
    General chemistry
    Chemistry (all)
    Astronomia / física

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