Author, as appears in the article.: Smirnova ES, Muñoz Molina JM, Johnson A, Bandeira NA, Bo C, Echavarren AM.
Department: Química Física i Inorgànica
URV's Author/s: Bo Jané, Carles / ECHAVARREN PABLOS, ANTONIO
Keywords: Ureas Urea Synthesis (chemical) Structure elucidation Silver halides Primary amines Phosphine-ligands Palladium Or Nanoparticles Nanoclusters Mild reaction conditions Homogeneous conditions Homogeneous catalysis Heterometallic complexes Gold nanoparticles Gold compounds Gold Crystal-structure Clusters Chemistry Catalyzed oxidative carbonylation Catalysis Catàlisi homogènia Carbonylation Carbonyl compounds Carbonilació C-h functionalization Bond Amines homogeneous catalysis heterometallic complexes gold carbonylation
Abstract: The synthesis of tetranuclear gold complexes, a structurally unprecedented octanuclear complex with a planar [Au(I) 8 ] core, and pentanuclear [Au(I) 4 M(I) ] (M=Cu, Ag) complexes is presented. The linear [Au(I) 4 ] complex undergoes C-H functionalization of carbonyl compounds under mild reaction conditions. In addition, [Au(I) 4 Ag(I) ] catalyzes the carbonylation of primary amines to form ureas under homogeneous conditions with efficiencies higher than those achieved by gold nanoparticles.© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Thematic Areas: Química Medicina ii Medicina i Materiais Interdisciplinar General medicine General chemistry Farmacia Engenharias ii Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Catalysis Astronomia / física
licence for use: https://creativecommons.org/licenses/by/3.0/es/
Author's mail: carles.bo@urv.cat antoniomaria.echavarren@urv.cat
Author identifier: 0000-0001-9581-2922 0000-0002-6418-7930
Record's date: 2024-09-07
Papper version: info:eu-repo/semantics/publishedVersion
Link to the original source: https://onlinelibrary.wiley.com/doi/10.1002/anie.201603200
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: Angewandte Chemie (International Ed. Print). 55 (26): 7487-7491
APA: Smirnova ES, Muñoz Molina JM, Johnson A, Bandeira NA, Bo C, Echavarren AM. (2016). Polynuclear Gold [AuI]4, [AuI]8, and Bimetallic [AuI 4AgI] Complexes: C-H Functionalization of Carbonyl Compounds and Homogeneous Carbonylation of Amines. Angewandte Chemie (International Ed. Print), 55(26), 7487-7491. DOI: 10.1002/anie.201603200
Article's DOI: 10.1002/anie.201603200
Entity: Universitat Rovira i Virgili
Journal publication year: 2016
Publication Type: Journal Publications
Repositori URV