Articles producció científica> Química Física i Inorgànica

Facile synthesis of NHC-stabilized Ni nanoparticles and their catalytic application in the Z-selective hydrogenation of alkynes

  • Dades identificatives

    Identificador: imarina:5131423
    Handle: https://hdl.handle.net/20.500.11797/imarina5131423
    Autors:
    Diaz de los Bernardos, MiriamPerez-Rodriguez, SaraGual, AitorClaver, CarmenGodard, Cyril
    Resum:
    Well defined Ni nanoparticles (NiNPs) stabilized with N-heterocyclic carbenes (NHCs) have been synthesized through a new methodology involving the decarboxylation of a zwitterionic CO2 adduct. Their catalytic performance was tested in the partial hydrogenation of alkynes into (Z)-alkenes under very mild reaction conditions (50 8C and 5 bar H2 pressure), providing excellent activities and selectivities.

  • Altres:

    Autor segons l'article: Diaz de los Bernardos, Miriam; Perez-Rodriguez, Sara; Gual, Aitor; Claver, Carmen; Godard, Cyril
    Departament: Química Física i Inorgànica
    e-ISSN: 1364-548X
    Autor/s de la URV: Claver Cabrero, Maria del Carmen Orosia / Godard, Cyril
    Codi de projecte: CTQ2016-75016-R
    Resum: Well defined Ni nanoparticles (NiNPs) stabilized with N-heterocyclic carbenes (NHCs) have been synthesized through a new methodology involving the decarboxylation of a zwitterionic CO2 adduct. Their catalytic performance was tested in the partial hydrogenation of alkynes into (Z)-alkenes under very mild reaction conditions (50 8C and 5 bar H2 pressure), providing excellent activities and selectivities.
    Àrees temàtiques: Surfaces, coatings and films Química Metals and alloys Medicina ii Medicina i Materials chemistry Materiais Interdisciplinar General medicine General chemistry Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Electronic, optical and magnetic materials Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Ceramics and composites Catalysis Biotecnología Biodiversidade Astronomia / física
    Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 1359-7345
    Adreça de correu electrònic de l'autor: cyril.godard@urv.cat carmen.claver@urv.cat
    Identificador de l'autor: 0000-0001-5762-4904 0000-0002-2518-7401
    Data d'alta del registre: 2024-10-12
    Programa de finançament 2: european; TERRA; 677471
    Versió de l'article dipositat: info:eu-repo/semantics/publishedVersion
    Programa de finançament: PROGRAMA ESTATAL DE INVESTIGACIÓN, DESARROLLO E INNOVACIÓN ORIENTADA A LOS RETOS DE LA SOCIEDAD
    URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referència a l'article segons font original: Chemical Communications. 53 (56): 7894-7897
    Referència de l'ítem segons les normes APA: Diaz de los Bernardos, Miriam; Perez-Rodriguez, Sara; Gual, Aitor; Claver, Carmen; Godard, Cyril (2017). Facile synthesis of NHC-stabilized Ni nanoparticles and their catalytic application in the Z-selective hydrogenation of alkynes. Chemical Communications, 53(56), 7894-7897. DOI: 10.1039/c7cc01779k
    Programa de finançament 3: plan; Retos; CTQ2016-75016-R, AEI/FEDER, UE
    Acrònim: ECO2VALCAT
    Entitat: Universitat Rovira i Virgili
    Any de publicació de la revista: 2017
    Acció del programa de finançament:  VALORIZACION EFICIENTE DE CO2 A COMBUSTIBLES Y COMPUESTOS DE ALTO VALOR AÑADIDO MEDIANTE CATALISIS HOMOGENEA Y NANO-CATALISIS
    Tipus de publicació: Journal Publications

  • Paraules clau:

    Catalysis,Ceramics and Composites,Chemistry,Chemistry (Miscellaneous),Chemistry, Multidisciplinary,Electronic, Optical and Magnetic Materials,Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films
    Surfaces, coatings and films
    Química
    Metals and alloys
    Medicina ii
    Medicina i
    Materials chemistry
    Materiais
    Interdisciplinar
    General medicine
    General chemistry
    Farmacia
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Engenharias i
    Electronic, optical and magnetic materials
    Ciências biológicas iii
    Ciências biológicas ii
    Ciências biológicas i
    Ciências ambientais
    Ciências agrárias i
    Chemistry, multidisciplinary
    Chemistry (miscellaneous)
    Chemistry (all)
    Chemistry
    Ceramics and composites
    Catalysis
    Biotecnología
    Biodiversidade
    Astronomia / física

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