Author, as appears in the article.: Diaz de los Bernardos, Miriam; Perez-Rodriguez, Sara; Gual, Aitor; Claver, Carmen; Godard, Cyril
Department: Química Física i Inorgànica
e-ISSN: 1364-548X
URV's Author/s: Claver Cabrero, Maria del Carmen Orosia / Godard, Cyril
Project code: CTQ2016-75016-R
Abstract: Well defined Ni nanoparticles (NiNPs) stabilized with N-heterocyclic carbenes (NHCs) have been synthesized through a new methodology involving the decarboxylation of a zwitterionic CO2 adduct. Their catalytic performance was tested in the partial hydrogenation of alkynes into (Z)-alkenes under very mild reaction conditions (50 8C and 5 bar H2 pressure), providing excellent activities and selectivities.
Thematic Areas: Surfaces, coatings and films Química Metals and alloys Medicina ii Medicina i Materials chemistry Materiais Interdisciplinar General medicine General chemistry Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Electronic, optical and magnetic materials Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Ceramics and composites Catalysis Biotecnología Biodiversidade Astronomia / física
licence for use: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 1359-7345
Author's mail: cyril.godard@urv.cat carmen.claver@urv.cat
Author identifier: 0000-0001-5762-4904 0000-0002-2518-7401
Record's date: 2024-10-12
Founding program 2: european; TERRA; 677471
Papper version: info:eu-repo/semantics/publishedVersion
Funding program: PROGRAMA ESTATAL DE INVESTIGACIÓN, DESARROLLO E INNOVACIÓN ORIENTADA A LOS RETOS DE LA SOCIEDAD
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: Chemical Communications. 53 (56): 7894-7897
APA: Diaz de los Bernardos, Miriam; Perez-Rodriguez, Sara; Gual, Aitor; Claver, Carmen; Godard, Cyril (2017). Facile synthesis of NHC-stabilized Ni nanoparticles and their catalytic application in the Z-selective hydrogenation of alkynes. Chemical Communications, 53(56), 7894-7897. DOI: 10.1039/c7cc01779k
Founding program 3: plan; Retos; CTQ2016-75016-R, AEI/FEDER, UE
Acronym: ECO2VALCAT
Entity: Universitat Rovira i Virgili
Journal publication year: 2017
Funding program action: VALORIZACION EFICIENTE DE CO2 A COMBUSTIBLES Y COMPUESTOS DE ALTO VALOR AÑADIDO MEDIANTE CATALISIS HOMOGENEA Y NANO-CATALISIS
Publication Type: Journal Publications