e-ISSN: 1364-548X

Project code: CTQ2016-75016-R

Record's date: 2023-02-18

Papper version: info:eu-repo/semantics/publishedVersion

Licence document URL: http://repositori.urv.cat/ca/proteccio-de-dades/

Papper original source: Chemical Communications. 53 (56): 7894-7897

APA: de Los Bernardos MD, Pérez-Rodríguez S, Gual A, Claver C, Godard C. (2017). Facile synthesis of NHC-stabilized Ni nanoparticles and their catalytic application in the Z-selective hydrogenation of alkynes. Chemical Communications, 53(56), 7894-7897. DOI: 10.1039/c7cc01779k

Acronym: ECO2VALCAT

Publication Type: Journal Publications

Author, as appears in the article.: de Los Bernardos MD, Pérez-Rodríguez S, Gual A, Claver C, Godard C.

Department: Química Física i Inorgànica

URV's Author/s: Claver Cabrero, Maria del Carmen Orosia / Godard, Cyril

Abstract: Well defined Ni nanoparticles (NiNPs) stabilized with N-heterocyclic carbenes (NHCs) have been synthesized through a new methodology involving the decarboxylation of a zwitterionic CO2 adduct. Their catalytic performance was tested in the partial hydrogenation of alkynes into (Z)-alkenes under very mild reaction conditions (50 8C and 5 bar H2 pressure), providing excellent activities and selectivities.

Thematic Areas: Surfaces, coatings and films Química Metals and alloys Medicina ii Medicina i Materials chemistry Materiais Interdisciplinar General medicine General chemistry Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Electronic, optical and magnetic materials Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Ceramics and composites Catalysis Biotecnología Biodiversidade Astronomia / física

licence for use: https://creativecommons.org/licenses/by/3.0/es/

ISSN: 1359-7345

Author's mail: carmen.claver@urv.cat cyril.godard@urv.cat

Author identifier: 0000-0002-2518-7401 0000-0001-5762-4904

Founding program 2: european; TERRA; 677471

Link to the original source: https://pubs.rsc.org/en/content/articlelanding/2017/cc/c7cc01779k#!divAbstract

Funding program: PROGRAMA ESTATAL DE INVESTIGACIÓN, DESARROLLO E INNOVACIÓN ORIENTADA A LOS RETOS DE LA SOCIEDAD

Founding program 3: plan; Retos; CTQ2016-75016-R, AEI/FEDER, UE

Article's DOI: 10.1039/c7cc01779k

Entity: Universitat Rovira i Virgili

Journal publication year: 2017

Funding program action:  VALORIZACION EFICIENTE DE CO2 A COMBUSTIBLES Y COMPUESTOS DE ALTO VALOR AÑADIDO MEDIANTE CATALISIS HOMOGENEA Y NANO-CATALISIS