Autor segons l'article: Guzmán D., Ramis X., Fernández-Francos X., De la Flor S., Serra A.
Departament: Química Analítica i Química Orgànica Enginyeria Mecànica
Autor/s de la URV: De la Flor Lopez, Silvia / Fernández Francos, Xavier / Serra Albet, Maria Angels
Paraules clau: Thermosets Structure-property relation Resins Renewable resources Oil Kinetics Crosslinking Clove Biopolymers Antioxidant activity Acid
Resum: A new triglycidyl eugenol derivative (3EPO-EU) was synthesized and characterized by spectroscopic techniques, and used as starting monomer in the preparation of novel bio-based thiol-epoxy thermosets. As thiols, commercially available tetrathiol derived from pentaerythritol (PETMP), a trithiol derived from eugenol (3SH-EU) and the hexathiol derived from squalene (6SH-SQ) were used in the presence of 4-(N,N-dimethylamino)pyridine as the basic catalyst. A flexible diglycidyl ether derived from hexanediol (2EPO-HEX) was also introduced in order to enhance conversion in formulations containing 6SH-SQ. The evolution of the curing was monitored by differential scanning calorimetry. The materials obtained are rigid at room temperature and showed Tgs up to 103 °C. The thermal stability, thermomechanical and mechanical properties were evaluated and discussed in terms of the structural characteristics of the resulting materials.
Àrees temàtiques: Surfaces, coatings and films Química Organic chemistry Materials science, coatings & films Materials chemistry Materiais Interdisciplinar General chemical engineering Engenharias iv Engenharias iii Engenharias ii Chemistry, applied Chemical engineering (miscellaneous) Chemical engineering (all)
ISSN: 03009440
Adreça de correu electrònic de l'autor: xavier.fernandez@urv.cat silvia.delaflor@urv.cat angels.serra@urv.cat
Identificador de l'autor: 0000-0002-3492-2922 0000-0002-6851-1371 0000-0003-1387-0358
Pàgina final: 267
Data d'alta del registre: 2023-02-18
Volum de revista: 114
Versió de l'article dipositat: info:eu-repo/semantics/acceptedVersion
Enllaç font original: https://www.sciencedirect.com/science/article/pii/S0300944017305726
URL Document de llicència: http://repositori.urv.cat/ca/proteccio-de-dades/
Referència a l'article segons font original: Progress In Organic Coatings. 114 259-267
Referència de l'ítem segons les normes APA: Guzmán D., Ramis X., Fernández-Francos X., De la Flor S., Serra A. (2018). Preparation of new biobased materials from a triglycidyl eugenol derivative through thiol-epoxy click reaction. Progress In Organic Coatings, 114(), 259-267. DOI: 10.1016/j.porgcoat.2017.10.025
DOI de l'article: 10.1016/j.porgcoat.2017.10.025
Entitat: Universitat Rovira i Virgili
Any de publicació de la revista: 2018
Pàgina inicial: 259
Tipus de publicació: Journal Publications
Repositori URV