Articles producció científica> Química Física i Inorgànica

Encapsulation of Chaotropic closo-Decahydrodecaborate Clusters Within Cyclodextrins: Synthesis, Solution Studies, and DFT Calculations

  • Dades identificatives

    Identificador: imarina:5874124
    Handle: https://hdl.handle.net/20.500.11797/imarina5874124
    Autors:
    Diab MFloquet SHaouas MAbramov PLópez XLandy DDamond AFalaise CGuérineau VTouboul DNaoufal DCadot E
    Resum:
    © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim This paper deals with the formation of host-guest systems between cyclodextrins and the closo-decahydrodecaborate cluster. The inclusion processes, although involving weak interaction, were evidenced in solution by ESI-MS and various NMR techniques. ITC measurements provided thermodynamic parameters, and DFT calculations gave some elements that help in understanding these processes.

  • Altres:

    Autor segons l'article: Diab M; Floquet S; Haouas M; Abramov P; López X; Landy D; Damond A; Falaise C; Guérineau V; Touboul D; Naoufal D; Cadot E
    Departament: Química Física i Inorgànica
    Autor/s de la URV: López Fernández, Javier
    Paraules clau: Structure elucidation Solvation Screening model Host-guest systems Host-guest chemistry Gamma-cyclodextrin Force Derivatives Cyclodextrins Complexation Chaotropes Boron Binding Beta-cyclodextrin Anion
    Resum: © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim This paper deals with the formation of host-guest systems between cyclodextrins and the closo-decahydrodecaborate cluster. The inclusion processes, although involving weak interaction, were evidenced in solution by ESI-MS and various NMR techniques. ITC measurements provided thermodynamic parameters, and DFT calculations gave some elements that help in understanding these processes.
    Àrees temàtiques: Química Medicina i Materiais Interdisciplinar Inorganic chemistry Farmacia Engenharias iii Engenharias ii Ciências biológicas ii Ciências biológicas i Chemistry, inorganic & nuclear Astronomia / física
    Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 14341948
    Adreça de correu electrònic de l'autor: javier.lopez@urv.cat
    Identificador de l'autor: 0000-0003-0322-6796
    Data d'alta del registre: 2023-02-18
    Versió de l'article dipositat: info:eu-repo/semantics/acceptedVersion
    Enllaç font original: https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/ejic.201900602
    Referència a l'article segons font original: European Journal Of Inorganic Chemistry. 2019 (29): 3373-3382
    Referència de l'ítem segons les normes APA: Diab M; Floquet S; Haouas M; Abramov P; López X; Landy D; Damond A; Falaise C; Guérineau V; Touboul D; Naoufal D; Cadot E (2019). Encapsulation of Chaotropic closo-Decahydrodecaborate Clusters Within Cyclodextrins: Synthesis, Solution Studies, and DFT Calculations. European Journal Of Inorganic Chemistry, 2019(29), 3373-3382. DOI: 10.1002/ejic.201900602
    URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
    DOI de l'article: 10.1002/ejic.201900602
    Entitat: Universitat Rovira i Virgili
    Any de publicació de la revista: 2019
    Tipus de publicació: Journal Publications

  • Paraules clau:

    Chemistry, Inorganic & Nuclear,Inorganic Chemistry
    Structure elucidation
    Solvation
    Screening model
    Host-guest systems
    Host-guest chemistry
    Gamma-cyclodextrin
    Force
    Derivatives
    Cyclodextrins
    Complexation
    Chaotropes
    Boron
    Binding
    Beta-cyclodextrin
    Anion
    Química
    Medicina i
    Materiais
    Interdisciplinar
    Inorganic chemistry
    Farmacia
    Engenharias iii
    Engenharias ii
    Ciências biológicas ii
    Ciências biológicas i
    Chemistry, inorganic & nuclear
    Astronomia / física

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