Articles producció científica> Química Física i Inorgànica

Encapsulation of Chaotropic closo-Decahydrodecaborate Clusters Within Cyclodextrins: Synthesis, Solution Studies, and DFT Calculations

  • Identification data

    Identifier: imarina:5874124
    Handle: https://hdl.handle.net/20.500.11797/imarina5874124
    Authors:
    Diab, ManalFloquet, SebastienHaouas, MohamedAbramov, Pavel ALopez, XavierLandy, DavidDamond, AurelieFalaise, ClementGuerineau, VincentTouboul, DavidNaoufal, DaoudCadot, Emmanuel
    Abstract:
    © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim This paper deals with the formation of host-guest systems between cyclodextrins and the closo-decahydrodecaborate cluster. The inclusion processes, although involving weak interaction, were evidenced in solution by ESI-MS and various NMR techniques. ITC measurements provided thermodynamic parameters, and DFT calculations gave some elements that help in understanding these processes.

  • Others:

    Author, as appears in the article.: Diab, Manal; Floquet, Sebastien; Haouas, Mohamed; Abramov, Pavel A; Lopez, Xavier; Landy, David; Damond, Aurelie; Falaise, Clement; Guerineau, Vincent; Touboul, David; Naoufal, Daoud; Cadot, Emmanuel
    Department: Química Física i Inorgànica
    URV's Author/s: López Fernández, Javier
    Keywords: Structure elucidation Solvation Screening model Host-guest systems Host-guest chemistry Gamma-cyclodextrin Force Derivatives Cyclodextrins Complexation Chaotropes Boron Binding Beta-cyclodextrin Anion
    Abstract: © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim This paper deals with the formation of host-guest systems between cyclodextrins and the closo-decahydrodecaborate cluster. The inclusion processes, although involving weak interaction, were evidenced in solution by ESI-MS and various NMR techniques. ITC measurements provided thermodynamic parameters, and DFT calculations gave some elements that help in understanding these processes.
    Thematic Areas: Química Medicina i Materiais Interdisciplinar Inorganic chemistry Farmacia Engenharias iii Engenharias ii Ciências biológicas ii Ciências biológicas i Chemistry, inorganic & nuclear Astronomia / física
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 14341948
    Author's mail: javier.lopez@urv.cat
    Author identifier: 0000-0003-0322-6796
    Record's date: 2025-02-18
    Paper version: info:eu-repo/semantics/acceptedVersion
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Paper original source: European Journal Of Inorganic Chemistry. 2019 (29): 3373-3382
    APA: Diab, Manal; Floquet, Sebastien; Haouas, Mohamed; Abramov, Pavel A; Lopez, Xavier; Landy, David; Damond, Aurelie; Falaise, Clement; Guerineau, Vincent (2019). Encapsulation of Chaotropic closo-Decahydrodecaborate Clusters Within Cyclodextrins: Synthesis, Solution Studies, and DFT Calculations. European Journal Of Inorganic Chemistry, 2019(29), 3373-3382. DOI: 10.1002/ejic.201900602
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2019
    Publication Type: Journal Publications

  • Keywords:

    Chemistry, Inorganic & Nuclear,Inorganic Chemistry
    Structure elucidation
    Solvation
    Screening model
    Host-guest systems
    Host-guest chemistry
    Gamma-cyclodextrin
    Force
    Derivatives
    Cyclodextrins
    Complexation
    Chaotropes
    Boron
    Binding
    Beta-cyclodextrin
    Anion
    Química
    Medicina i
    Materiais
    Interdisciplinar
    Inorganic chemistry
    Farmacia
    Engenharias iii
    Engenharias ii
    Ciências biológicas ii
    Ciências biológicas i
    Chemistry, inorganic & nuclear
    Astronomia / física

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