Articles producció científica> Enginyeria Mecànica

Shape-memory actuators based on dual-curing thiol-acrylate-epoxy thermosets

  • Dades identificatives

    Identificador: imarina:9138868
    Autors:
    Russo CFernandez-Francos XDe la Flor S
    Resum:
    © BME-PT. In this work, new shape-memory thermosets have been developed using a thiol-acrylate-epoxy dual-curing system. A previously studied system has been successfully modified, introducing different amounts of tri(2,3-epoxypropyl)isocya-nurate (ISO) and bisphenol A glycerolate (1 glycerol/phenol) diacrylate (BAGA) in order to enhance the thermomechanical properties and the glass transition temperature of the final materials. Preliminary studies on the curing process proved that the curing process is not affected, and the critical ratio remains unchanged. Glass transition temperatures and thermome-chanical properties were successfully improved, extending the applicability of these thermosets to the field of soft-actuator. Shape-memory behavior was comprehensively investigated in unconstrained, fully and partially constrained conditions. Unconstrained experiment results showed excellent shape fixation and recovery, coupled with a fast recovery process. On the other hand, fully and partially constrained recovery experiments evidenced optimal performances obtained by the combination of both high crosslinking density and high deformability in the programming stage. Considerably high values of recovery stress (up to 7 MPa) and work output (up to 1300 kJ/m3) were found confirming the high potentiality of these dual-cured thermosets in the field of soft-actuation.
  • Altres:

    Autor segons l'article: Russo C; Fernandez-Francos X; De la Flor S
    Departament: Enginyeria Mecànica
    Autor/s de la URV: De la Flor Lopez, Silvia / Fernández Francos, Xavier / Russo, Claudio
    Paraules clau: Thermosetting resins Shape-memory Recovery stress Dual-curing Actuator
    Resum: © BME-PT. In this work, new shape-memory thermosets have been developed using a thiol-acrylate-epoxy dual-curing system. A previously studied system has been successfully modified, introducing different amounts of tri(2,3-epoxypropyl)isocya-nurate (ISO) and bisphenol A glycerolate (1 glycerol/phenol) diacrylate (BAGA) in order to enhance the thermomechanical properties and the glass transition temperature of the final materials. Preliminary studies on the curing process proved that the curing process is not affected, and the critical ratio remains unchanged. Glass transition temperatures and thermome-chanical properties were successfully improved, extending the applicability of these thermosets to the field of soft-actuator. Shape-memory behavior was comprehensively investigated in unconstrained, fully and partially constrained conditions. Unconstrained experiment results showed excellent shape fixation and recovery, coupled with a fast recovery process. On the other hand, fully and partially constrained recovery experiments evidenced optimal performances obtained by the combination of both high crosslinking density and high deformability in the programming stage. Considerably high values of recovery stress (up to 7 MPa) and work output (up to 1300 kJ/m3) were found confirming the high potentiality of these dual-cured thermosets in the field of soft-actuation.
    Àrees temàtiques: Química Polymers and plastics Polymer science Physical and theoretical chemistry Organic chemistry Odontología Materials chemistry Materiais Interdisciplinar General chemical engineering Farmacia Engenharias iv Engenharias iii Engenharias ii Ciências biológicas iii Ciências biológicas i Ciências ambientais Chemical engineering (miscellaneous) Chemical engineering (all) Biotecnología Astronomia / física
    Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 1788618X
    Adreça de correu electrònic de l'autor: xavier.fernandez@urv.cat silvia.delaflor@urv.cat
    Identificador de l'autor: 0000-0002-3492-2922 0000-0002-6851-1371
    Data d'alta del registre: 2024-07-27
    Versió de l'article dipositat: info:eu-repo/semantics/publishedVersion
    Enllaç font original: http://www.expresspolymlett.com/
    URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referència a l'article segons font original: Express Polymer Letters. 15 (1): 58-71
    Referència de l'ítem segons les normes APA: Russo C; Fernandez-Francos X; De la Flor S (2021). Shape-memory actuators based on dual-curing thiol-acrylate-epoxy thermosets. Express Polymer Letters, 15(1), 58-71. DOI: 10.3144/expresspolymlett.2021.7
    DOI de l'article: 10.3144/expresspolymlett.2021.7
    Entitat: Universitat Rovira i Virgili
    Any de publicació de la revista: 2021
    Tipus de publicació: Journal Publications
  • Paraules clau:

    Chemical Engineering (Miscellaneous),Materials Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Polymer Science,Polymers and Plastics
    Thermosetting resins
    Shape-memory
    Recovery stress
    Dual-curing
    Actuator
    Química
    Polymers and plastics
    Polymer science
    Physical and theoretical chemistry
    Organic chemistry
    Odontología
    Materials chemistry
    Materiais
    Interdisciplinar
    General chemical engineering
    Farmacia
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Ciências biológicas iii
    Ciências biológicas i
    Ciências ambientais
    Chemical engineering (miscellaneous)
    Chemical engineering (all)
    Biotecnología
    Astronomia / física
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