Autor según el artículo: Russo C; Fernandez-Francos X; De la Flor S
Departamento: Enginyeria Mecànica
Autor/es de la URV: De la Flor Lopez, Silvia / Fernández Francos, Xavier / Russo, Claudio
Palabras clave: Thermosetting resins Shape-memory Recovery stress Dual-curing Actuator
Resumen: © BME-PT. In this work, new shape-memory thermosets have been developed using a thiol-acrylate-epoxy dual-curing system. A previously studied system has been successfully modified, introducing different amounts of tri(2,3-epoxypropyl)isocya-nurate (ISO) and bisphenol A glycerolate (1 glycerol/phenol) diacrylate (BAGA) in order to enhance the thermomechanical properties and the glass transition temperature of the final materials. Preliminary studies on the curing process proved that the curing process is not affected, and the critical ratio remains unchanged. Glass transition temperatures and thermome-chanical properties were successfully improved, extending the applicability of these thermosets to the field of soft-actuator. Shape-memory behavior was comprehensively investigated in unconstrained, fully and partially constrained conditions. Unconstrained experiment results showed excellent shape fixation and recovery, coupled with a fast recovery process. On the other hand, fully and partially constrained recovery experiments evidenced optimal performances obtained by the combination of both high crosslinking density and high deformability in the programming stage. Considerably high values of recovery stress (up to 7 MPa) and work output (up to 1300 kJ/m3) were found confirming the high potentiality of these dual-cured thermosets in the field of soft-actuation.
Áreas temáticas: Química Polymers and plastics Polymer science Physical and theoretical chemistry Organic chemistry Odontología Materials chemistry Materiais Interdisciplinar General chemical engineering Farmacia Engenharias iv Engenharias iii Engenharias ii Ciências biológicas iii Ciências biológicas i Ciências ambientais Chemical engineering (miscellaneous) Chemical engineering (all) Biotecnología Astronomia / física
Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 1788618X
Direcció de correo del autor: xavier.fernandez@urv.cat silvia.delaflor@urv.cat
Identificador del autor: 0000-0002-3492-2922 0000-0002-6851-1371
Fecha de alta del registro: 2024-07-27
Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
Enlace a la fuente original: http://www.expresspolymlett.com/
URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
Referencia al articulo segun fuente origial: Express Polymer Letters. 15 (1): 58-71
Referencia de l'ítem segons les normes APA: Russo C; Fernandez-Francos X; De la Flor S (2021). Shape-memory actuators based on dual-curing thiol-acrylate-epoxy thermosets. Express Polymer Letters, 15(1), 58-71. DOI: 10.3144/expresspolymlett.2021.7
DOI del artículo: 10.3144/expresspolymlett.2021.7
Entidad: Universitat Rovira i Virgili
Año de publicación de la revista: 2021
Tipo de publicación: Journal Publications