Autor segons l'article: Mato, Mauro; Franchino, Allegra; Garcia-Morales, Cristina; Echavarren, Antonio M
Departament: Geografia
Autor/s de la URV: ECHAVARREN PABLOS, ANTONIO / Mato Gómez, Mauro / Muro Morales, José Ignacio
Paraules clau: asymmetric cyclopropanation; carbene-transfer-reactions; gold(i)-catalyzed cycloisomerization; n-heterocyclic carbenes; nitrene transfer-reactions; oxidative cyclization; propargylic esters; retro-buchner reaction; skeletal rearrangement; Enantioselective 2+2 cycloaddition
Resum: © Three- and four-membered rings, widespread motifs in nature and medicinal chemistry, have fascinated chemists ever since their discovery. However, due to energetic considerations, small rings are often difficult to assemble. In this regard, homogeneous gold catalysis has emerged as a powerful tool to construct these highly strained carbocycles. This review aims to provide a comprehensive summary of all the major advances and discoveries made in the gold-catalyzed synthesis of cyclopropanes, cyclopropenes, cyclobutanes, cyclobutenes, and their corresponding heterocyclic or heterosubstituted analogs.
Àrees temàtiques: Biotecnología; Chemistry; Chemistry (all); Chemistry (miscellaneous); Chemistry, multidisciplinary; Ciência de alimentos; Ciências biológicas i; Ciências biológicas ii; Engenharias ii; Engenharias iii; Farmacia; General chemistry; General medicine; Materiais; Química
Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
Adreça de correu electrònic de l'autor: antoniomaria.echavarren@urv.cat; joseignacio.muro@urv.cat
Data d'alta del registre: 2025-02-18
Versió de l'article dipositat: info:eu-repo/semantics/publishedVersion
Enllaç font original: https://pubs.acs.org/doi/10.1021/acs.chemrev.0c00697
Referència a l'article segons font original: Chemical Reviews. 121 (14): 8613-8684
Referència de l'ítem segons les normes APA: Mato, Mauro; Franchino, Allegra; Garcia-Morales, Cristina; Echavarren, Antonio M (2021). Gold-Catalyzed Synthesis of Small Rings. Chemical Reviews, 121(14), 8613-8684. DOI: 10.1021/acs.chemrev.0c00697
URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
DOI de l'article: 10.1021/acs.chemrev.0c00697
Entitat: Universitat Rovira i Virgili
Any de publicació de la revista: 2021
Tipus de publicació: info:eu-repo/semantics/article
Repositori URV