Autor segons l'article: Cuenca AB; Fernández E
Departament: Química Física i Inorgànica
e-ISSN: 1460-4744
Autor/s de la URV: Fernández Gutiérrez, Maria Elena
Paraules clau: Stereoselective-synthesis Ketones Generation Esters Deprotonation Carbonyl-compounds Carbanions Bis(ethylenedioxyboryl)methide Aldehydes
Resum: © The Royal Society of Chemistry. The condensation of easy manageable lithium α-bis(boryl)carbanions with carbonyl derivatives, the so-called boron-Wittig reaction, allows for the straightforward and often stereoselective formation of synthetically highly versatile metalloid-substituted alkenes, which are key building blocks on route to all-carbon substituted olefins. In this Tutorial review the concept behind this olefination reaction and its application to ketones, aldehydes and other carbonyl derivatives, such amides, ester and carboxylic acids, are presented in a systematic manner. A special emphasis has been placed on parameters controlling the stereochemical outcome of these transformations. To illustrate the great synthetic potential of this new methodological tool, a section is also included covering a selection of applications of the boron-Wittig reaction to target compounds via subsequent C-C bond-forming process. This journal is
Àrees temàtiques: Química Materiais General medicine General chemistry Ciências biológicas ii Ciência de alimentos Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Antropologia / arqueologia
Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 0306-0012
Adreça de correu electrònic de l'autor: mariaelena.fernandez@urv.cat
Identificador de l'autor: 0000-0001-9025-1791
Data d'alta del registre: 2024-07-27
Versió de l'article dipositat: info:eu-repo/semantics/acceptedVersion
Enllaç font original: https://pubs.rsc.org/en/content/articlelanding/2021/cs/d0cs00953a#!divAbstract
URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
Referència a l'article segons font original: Chemical Society Reviews. 50 (1): 72-86
Referència de l'ítem segons les normes APA: Cuenca AB; Fernández E (2021). Boron-Wittig olefination with: Gem -bis(boryl)alkanes. Chemical Society Reviews, 50(1), 72-86. DOI: 10.1039/d0cs00953a
DOI de l'article: 10.1039/d0cs00953a
Entitat: Universitat Rovira i Virgili
Any de publicació de la revista: 2021
Tipus de publicació: Journal Publications
Repositori URV