Autor segons l'article: Jaramillo-Fierro X; González S; Medina F
Departament: Enginyeria Química
Autor/s de la URV: Medina Cabello, Francisco
Paraules clau: Zntio 3 Tio2 Tio 2 Photocatalysis Methylene-blue dye La-doping Heterojunction Absorption zntio3 zno nanoparticles waste-water tio2 nanoparticles synthesize nitrogen surface modification rhodamine-b removal photocatalysis la-doping heterojunction aqueous-solutions adsorption properties absorption
Resum: Currently, there is great interest in the use of TiO2 for photocatalytic remediation of wastewater. Doping, heterojunction, and immobilization on porous materials are effective methods to improve the photocatalytic efficiency of this semiconductor oxide. In this study, ZnTiO3 /TiO2 (ZTO) and ZnTiO3 /TiO2 /La (ZTO/La) nanocomposites were successfully prepared and immobilized on diatomaceous earth (DE). The composition and texture of the composites prepared were characterized by X-ray diffraction (XRD), X-ray fluorescence (XRF), diffuse reflectance spectroscopy (DRS), scanning electron microscopy (SEM-EDX), and specific surface area (SSA). The adsorption capacity and photocatalytic activity of the composites were determined via degradation of methylene blue (MB) in batch reactors. The materials evaluated were prepared in the shape of 0.2 cm (diameter) and 1.0 cm (length) cylindrical extrudates. The results indicate that the ZTO/La-DE composite exhibited higher efficiency for the removal of MB under solar irradiation than both ZTO-DE and DE. The pseudo-second-order model and the Langmuir isotherm model were better suited to explain the adsorption process. The highest degradation percentage of MB obtained was 96% after 150 min of irradiation. The results indicate that synthesized composite could be used for the removal of cationic dyes in wastewater.
Àrees temàtiques: Zootecnia / recursos pesqueiros Saúde coletiva Química Psicología Planejamento urbano e regional / demografia Physical and theoretical chemistry Pharmaceutical science Organic chemistry Odontología Nutrição Molecular medicine Medicine (miscellaneous) Medicina veterinaria Medicina iii Medicina ii Medicina i Materiais Matemática / probabilidade e estatística Interdisciplinar Geografía General medicine Farmacia Ensino Engenharias iv Engenharias iii Engenharias ii Engenharias i Educação física Economia Drug discovery Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Ciência de alimentos Ciência da computação Chemistry, organic Chemistry, multidisciplinary Chemistry (miscellaneous) Biotecnología Biodiversidade Biochemistry & molecular biology Astronomia / física Analytical chemistry
Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
Adreça de correu electrònic de l'autor: francesc.medina@urv.cat
Identificador de l'autor: 0000-0002-3111-1542
Data d'alta del registre: 2024-07-27
Versió de l'article dipositat: info:eu-repo/semantics/publishedVersion
Enllaç font original: https://www.mdpi.com/1420-3049/26/20/6232
URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
Referència a l'article segons font original: Molecules. 26 (20):
Referència de l'ítem segons les normes APA: Jaramillo-Fierro X; González S; Medina F (2021). La-doped zntio3 /tio2 nanocomposite supported on ecuadorian diatomaceous earth as a highly efficient photocatalyst driven by solar light. Molecules, 26(20), -. DOI: 10.3390/molecules26206232
DOI de l'article: 10.3390/molecules26206232
Entitat: Universitat Rovira i Virgili
Any de publicació de la revista: 2021
Tipus de publicació: Journal Publications
Repositori URV