Articles producció científica> Enginyeria Química

La-doped zntio3 /tio2 nanocomposite supported on ecuadorian diatomaceous earth as a highly efficient photocatalyst driven by solar light

  • Identification data

    Identifier: imarina:9230633
    Authors:
    Jaramillo-Fierro XGonzález SMedina F
    Abstract:
    Currently, there is great interest in the use of TiO2 for photocatalytic remediation of wastewater. Doping, heterojunction, and immobilization on porous materials are effective methods to improve the photocatalytic efficiency of this semiconductor oxide. In this study, ZnTiO3 /TiO2 (ZTO) and ZnTiO3 /TiO2 /La (ZTO/La) nanocomposites were successfully prepared and immobilized on diatomaceous earth (DE). The composition and texture of the composites prepared were characterized by X-ray diffraction (XRD), X-ray fluorescence (XRF), diffuse reflectance spectroscopy (DRS), scanning electron microscopy (SEM-EDX), and specific surface area (SSA). The adsorption capacity and photocatalytic activity of the composites were determined via degradation of methylene blue (MB) in batch reactors. The materials evaluated were prepared in the shape of 0.2 cm (diameter) and 1.0 cm (length) cylindrical extrudates. The results indicate that the ZTO/La-DE composite exhibited higher efficiency for the removal of MB under solar irradiation than both ZTO-DE and DE. The pseudo-second-order model and the Langmuir isotherm model were better suited to explain the adsorption process. The highest degradation percentage of MB obtained was 96% after 150 min of irradiation. The results indicate that synthesized composite could be used for the removal of cationic dyes in wastewater.
  • Others:

    Author, as appears in the article.: Jaramillo-Fierro X; González S; Medina F
    Department: Enginyeria Química
    URV's Author/s: Medina Cabello, Francisco
    Keywords: Zntio 3 Tio2 Tio 2 Photocatalysis Methylene-blue dye La-doping Heterojunction Absorption zntio3 zno nanoparticles waste-water tio2 nanoparticles synthesize nitrogen surface modification rhodamine-b removal photocatalysis la-doping heterojunction aqueous-solutions adsorption properties absorption
    Abstract: Currently, there is great interest in the use of TiO2 for photocatalytic remediation of wastewater. Doping, heterojunction, and immobilization on porous materials are effective methods to improve the photocatalytic efficiency of this semiconductor oxide. In this study, ZnTiO3 /TiO2 (ZTO) and ZnTiO3 /TiO2 /La (ZTO/La) nanocomposites were successfully prepared and immobilized on diatomaceous earth (DE). The composition and texture of the composites prepared were characterized by X-ray diffraction (XRD), X-ray fluorescence (XRF), diffuse reflectance spectroscopy (DRS), scanning electron microscopy (SEM-EDX), and specific surface area (SSA). The adsorption capacity and photocatalytic activity of the composites were determined via degradation of methylene blue (MB) in batch reactors. The materials evaluated were prepared in the shape of 0.2 cm (diameter) and 1.0 cm (length) cylindrical extrudates. The results indicate that the ZTO/La-DE composite exhibited higher efficiency for the removal of MB under solar irradiation than both ZTO-DE and DE. The pseudo-second-order model and the Langmuir isotherm model were better suited to explain the adsorption process. The highest degradation percentage of MB obtained was 96% after 150 min of irradiation. The results indicate that synthesized composite could be used for the removal of cationic dyes in wastewater.
    Thematic Areas: Zootecnia / recursos pesqueiros Saúde coletiva Química Psicología Planejamento urbano e regional / demografia Physical and theoretical chemistry Pharmaceutical science Organic chemistry Odontología Nutrição Molecular medicine Medicine (miscellaneous) Medicina veterinaria Medicina iii Medicina ii Medicina i Materiais Matemática / probabilidade e estatística Interdisciplinar Geografía General medicine Farmacia Ensino Engenharias iv Engenharias iii Engenharias ii Engenharias i Educação física Economia Drug discovery Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Ciência de alimentos Ciência da computação Chemistry, organic Chemistry, multidisciplinary Chemistry (miscellaneous) Biotecnología Biodiversidade Biochemistry & molecular biology Astronomia / física Analytical chemistry
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Author's mail: francesc.medina@urv.cat
    Author identifier: 0000-0002-3111-1542
    Record's date: 2024-07-27
    Papper version: info:eu-repo/semantics/publishedVersion
    Link to the original source: https://www.mdpi.com/1420-3049/26/20/6232
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Papper original source: Molecules. 26 (20):
    APA: Jaramillo-Fierro X; González S; Medina F (2021). La-doped zntio3 /tio2 nanocomposite supported on ecuadorian diatomaceous earth as a highly efficient photocatalyst driven by solar light. Molecules, 26(20), -. DOI: 10.3390/molecules26206232
    Article's DOI: 10.3390/molecules26206232
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2021
    Publication Type: Journal Publications
  • Keywords:

    Analytical Chemistry,Biochemistry & Molecular Biology,Chemistry (Miscellaneous),Chemistry, Multidisciplinary,Chemistry, Organic,Drug Discovery,Medicine (Miscellaneous),Molecular Medicine,Organic Chemistry,Pharmaceutical Science,Physical and Theoretical Chemistry
    Zntio 3
    Tio2
    Tio 2
    Photocatalysis
    Methylene-blue dye
    La-doping
    Heterojunction
    Absorption
    zntio3
    zno nanoparticles
    waste-water
    tio2 nanoparticles
    synthesize nitrogen
    surface modification
    rhodamine-b
    removal
    photocatalysis
    la-doping
    heterojunction
    aqueous-solutions
    adsorption properties
    absorption
    Zootecnia / recursos pesqueiros
    Saúde coletiva
    Química
    Psicología
    Planejamento urbano e regional / demografia
    Physical and theoretical chemistry
    Pharmaceutical science
    Organic chemistry
    Odontología
    Nutrição
    Molecular medicine
    Medicine (miscellaneous)
    Medicina veterinaria
    Medicina iii
    Medicina ii
    Medicina i
    Materiais
    Matemática / probabilidade e estatística
    Interdisciplinar
    Geografía
    General medicine
    Farmacia
    Ensino
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Engenharias i
    Educação física
    Economia
    Drug discovery
    Ciências biológicas iii
    Ciências biológicas ii
    Ciências biológicas i
    Ciências ambientais
    Ciências agrárias i
    Ciência de alimentos
    Ciência da computação
    Chemistry, organic
    Chemistry, multidisciplinary
    Chemistry (miscellaneous)
    Biotecnología
    Biodiversidade
    Biochemistry & molecular biology
    Astronomia / física
    Analytical chemistry
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