Autor segons l'article: Li X; Villar-Yanez A; Ngassam Tounzoua C; Benet-Buchholz J; Grignard B; Bo C; Detrembleur C; Kleij AW
Departament: Química Física i Inorgànica
Autor/s de la URV: Benet Buchholz, Jordi / Bo Jané, Carles / Villar Yanez, Alba
Paraules clau: Ring-opening polymerization Homogeneous catalysis Heterocycles Cascade reactions Carbon dioxide Alkyne-1,n-diols Alkyne-1, n-diols rearrangement propargylic alcohols homogeneous catalysis heterocycles epoxides diols conversion co2 chemicals catalytic strategies cascade reactions carbon dioxide atmospheric-pressure
Resum: A silver-catalyzed cascade conversion of modular alkyne-1,n-diols and carbon dioxide has been developed allowing for the selective formation of keto-functionalized cyclic carbonates. The protocol is characterized by its operational simplicity, excellent scope of carbonate-based heterocycles, and mild reaction conditions. In situ IR studies, control experiments, and detailed computational analysis of these manifolds reveal the intermediacy of an α-alkylidene carbonate that is intercepted by an intramolecular alcohol nucleophile. The synthetic potential of this conceptually attractive CO2 transformation is demonstrated in the preparation of larger ring carbonates and their thermal rearrangement to sterically crowded, five-membered fused carbonate products.
Àrees temàtiques: Química Materiais Interdisciplinar General chemistry Engenharias ii Ciências agrárias i Chemistry, physical Chemistry (miscellaneous) Chemistry (all) Catalysis Astronomia / física
Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
Adreça de correu electrònic de l'autor: carles.bo@urv.cat alba.villar@estudiants.urv.cat
Identificador de l'autor: 0000-0001-9581-2922
Data d'alta del registre: 2024-09-07
Versió de l'article dipositat: info:eu-repo/semantics/publishedVersion
Enllaç font original: https://pubs.acs.org/doi/10.1021/acscatal.1c05773
URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
Referència a l'article segons font original: Acs Catalysis. 12 (5): 2854-2860
Referència de l'ítem segons les normes APA: Li X; Villar-Yanez A; Ngassam Tounzoua C; Benet-Buchholz J; Grignard B; Bo C; Detrembleur C; Kleij AW (2022). Cascade Transformation of Carbon Dioxide and Alkyne-1, n-diols into Densely Substituted Cyclic Carbonates. Acs Catalysis, 12(5), 2854-2860. DOI: 10.1021/acscatal.1c05773
DOI de l'article: 10.1021/acscatal.1c05773
Entitat: Universitat Rovira i Virgili
Any de publicació de la revista: 2022
Tipus de publicació: Journal Publications
Repositori URV