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Planar Chiral 1,3-Disubstituted Ferrocenyl Phosphine Gold(I) Catalysts

  • Dades identificatives

    Identificador: imarina:9247338
    Autors:
    Caniparoli UEscofet IEchavarren AM
    Resum:
    Planar chiral monodentate 1,3-disubstituted ferrocene phosphines inspired on JohnPhos-type ligands have been synthesized and applied to the enantioselective gold(I) catalyzed [4 + 2] cycloaddition of 1,6-arylenynes. Computational studies rationalized the working mode of the catalyst on the folding of the substrate in the chiral environment of the ligand involving attractive noncovalent interactions.
  • Altres:

    Autor segons l'article: Caniparoli U; Escofet I; Echavarren AM
    Departament: Química Analítica i Química Orgànica
    Autor/s de la URV: Caniparoli, Ulysse Grégoire / ECHAVARREN PABLOS, ANTONIO
    Paraules clau: Planar chirality Keywords Gold catalysis Ferrocene phosphines Enynes Enantioselective synthesis Dft calculations Asymmetric-synthesis planar chirality ligands hydrosilylation gold catalysis ferrocene phosphines errocene phosphines enynes enantioselective synthesis dft calculations
    Resum: Planar chiral monodentate 1,3-disubstituted ferrocene phosphines inspired on JohnPhos-type ligands have been synthesized and applied to the enantioselective gold(I) catalyzed [4 + 2] cycloaddition of 1,6-arylenynes. Computational studies rationalized the working mode of the catalyst on the folding of the substrate in the chiral environment of the ligand involving attractive noncovalent interactions.
    Àrees temàtiques: Química Materiais Interdisciplinar General chemistry Engenharias ii Ciências agrárias i Chemistry, physical Chemistry (miscellaneous) Chemistry (all) Catalysis Astronomia / física
    Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
    Adreça de correu electrònic de l'autor: antoniomaria.echavarren@urv.cat ulysse.caniparoli@estudiants.urv.cat
    Identificador de l'autor: 0000-0002-6418-7930
    Data d'alta del registre: 2024-09-07
    Versió de l'article dipositat: info:eu-repo/semantics/publishedVersion
    Enllaç font original: https://pubs.acs.org/doi/10.1021/acscatal.1c05827
    URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referència a l'article segons font original: Acs Catalysis. 12 (6): 3317-3322
    Referència de l'ítem segons les normes APA: Caniparoli U; Escofet I; Echavarren AM (2022). Planar Chiral 1,3-Disubstituted Ferrocenyl Phosphine Gold(I) Catalysts. Acs Catalysis, 12(6), 3317-3322. DOI: 10.1021/acscatal.1c05827
    DOI de l'article: 10.1021/acscatal.1c05827
    Entitat: Universitat Rovira i Virgili
    Any de publicació de la revista: 2022
    Tipus de publicació: Journal Publications
  • Paraules clau:

    Catalysis,Chemistry (Miscellaneous),Chemistry, Physical
    Planar chirality
    Keywords
    Gold catalysis
    Ferrocene phosphines
    Enynes
    Enantioselective synthesis
    Dft calculations
    Asymmetric-synthesis
    planar chirality
    ligands
    hydrosilylation
    gold catalysis
    ferrocene phosphines
    errocene phosphines
    enynes
    enantioselective synthesis
    dft calculations
    Química
    Materiais
    Interdisciplinar
    General chemistry
    Engenharias ii
    Ciências agrárias i
    Chemistry, physical
    Chemistry (miscellaneous)
    Chemistry (all)
    Catalysis
    Astronomia / física
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