Author, as appears in the article.: Caniparoli U; Escofet I; Echavarren AM
Department: Química Analítica i Química Orgànica
URV's Author/s: Caniparoli, Ulysse Grégoire / ECHAVARREN PABLOS, ANTONIO
Keywords: Planar chirality Keywords Gold catalysis Ferrocene phosphines Enynes Enantioselective synthesis Dft calculations Asymmetric-synthesis planar chirality ligands hydrosilylation gold catalysis ferrocene phosphines errocene phosphines enynes enantioselective synthesis dft calculations
Abstract: Planar chiral monodentate 1,3-disubstituted ferrocene phosphines inspired on JohnPhos-type ligands have been synthesized and applied to the enantioselective gold(I) catalyzed [4 + 2] cycloaddition of 1,6-arylenynes. Computational studies rationalized the working mode of the catalyst on the folding of the substrate in the chiral environment of the ligand involving attractive noncovalent interactions.
Thematic Areas: Química Materiais Interdisciplinar General chemistry Engenharias ii Ciências agrárias i Chemistry, physical Chemistry (miscellaneous) Chemistry (all) Catalysis Astronomia / física
licence for use: https://creativecommons.org/licenses/by/3.0/es/
Author's mail: antoniomaria.echavarren@urv.cat ulysse.caniparoli@estudiants.urv.cat
Author identifier: 0000-0002-6418-7930
Record's date: 2024-09-07
Papper version: info:eu-repo/semantics/publishedVersion
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: Acs Catalysis. 12 (6): 3317-3322
APA: Caniparoli U; Escofet I; Echavarren AM (2022). Planar Chiral 1,3-Disubstituted Ferrocenyl Phosphine Gold(I) Catalysts. Acs Catalysis, 12(6), 3317-3322. DOI: 10.1021/acscatal.1c05827
Entity: Universitat Rovira i Virgili
Journal publication year: 2022
Publication Type: Journal Publications
Repositori URV