Articles producció científicaQuímica Analítica i Química Orgànica

Planar Chiral 1

  • Identification data

    Identifier:  imarina:9247338
    Handle: https://hdl.handle.net/20.500.11797/imarina9247338
    Authors:  Caniparoli, Ulysse; Escofet, Imma; Echavarren, Antonio M
    Abstract:
    Planar chiral monodentate 1,3-disubstituted ferrocene phosphines inspired on JohnPhos-type ligands have been synthesized and applied to the enantioselective gold(I) catalyzed [4 + 2] cycloaddition of 1,6-arylenynes. Computational studies rationalized the working mode of the catalyst on the folding of the substrate in the chiral environment of the ligand involving attractive noncovalent interactions.

  • Others:

    Link to the original source: https://pubs.acs.org/doi/10.1021/acscatal.1c05827
    APA: Caniparoli, Ulysse; Escofet, Imma; Echavarren, Antonio M (2022). Planar Chiral 1,3-Disubstituted Ferrocenyl Phosphine Gold(I) Catalysts. Acs Catalysis, 12(6), 3317-3322. DOI: 10.1021/acscatal.1c05827
    Paper original source: Acs Catalysis. 12 (6): 3317-3322
    Article's DOI: 10.1021/acscatal.1c05827
    Journal publication year: 2022
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/publishedVersion
    Record's date: 2025-02-18
    URV's Author/s: Caniparoli, Ulysse Grégoire / ECHAVARREN PABLOS, ANTONIO
    Department: Química Analítica i Química Orgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Journal Publications
    Author, as appears in the article.: Caniparoli, Ulysse; Escofet, Imma; Echavarren, Antonio M
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Thematic Areas: Química, Materiais, Interdisciplinar, General chemistry, Engenharias ii, Ciências agrárias i, Chemistry, physical, Chemistry (miscellaneous), Chemistry (all), Catalysis, Astronomia / física
    Author's mail: antoniomaria.echavarren@urv.cat, ulysse.caniparoli@estudiants.urv.cat

  • Keywords:

    Planar chirality
    Keywords
    Gold catalysis
    Ferrocene phosphines
    Enynes
    Enantioselective synthesis
    Dft calculations
    Asymmetric-synthesis
    ligands
    hydrosilylation
    errocene phosphines
    Catalysis
    Chemistry (Miscellaneous)
    Chemistry
    Physical
    Química
    Materiais
    Interdisciplinar
    General chemistry
    Engenharias ii
    Ciências agrárias i
    Chemistry (all)
    Astronomia / física

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