Articles producció científica> Química Física i Inorgànica

Tm,Ho:Ca(Gd,Lu)AlO4 crystals: Crystal growth, structure refinement and Judd-Ofelt analysis

  • Dades identificatives

    Identificador: imarina:9247875
    Autors:
    Pan ZLoiko PSlimi SYuan HWang YZhao YCamy PDunina EKornienko AFomicheva LWang LChen WGriebner UPetrov VSolé RMDíaz FAguiló MMateos X
    Resum:
    “Mixed” calcium rare-earth aluminate laser host crystals Ca(Gd,Lu)AlO4 (CALGLO) with up to 10.8 at.% Lu codoped with Tm3+ and Ho3+ ions are grown by the Czochralski method along the [001] direction. The segregation of rare-earth ions is studied. The crystal structure is refined by the Rietveld method. Tm,Ho:Ca(Gd,Lu)AlO4 crystallizes in the tetragonal system (sp. gr. I4/mmm) exhibiting a K2NiF4 type structure. The lattice constants are a = 3.6585(6) Å and c = 11.9660(9) Å for a crystal with a composition of CaGd0.8947Lu0.0551Tm0.0448Ho0.0054AlO4. The stability of Ca(Gd,Lu)AlO4 solid-solutions is discussed. The polarized Raman spectra are measured, revealing a most intense mode at 311 cm−1 and a maximum phonon frequency of ∼650 cm−1. The polarized absorption spectra are measured. The transition intensities for the Ho3+ ion are analyzed using the modified Judd-Ofelt theory accounting for configuration interaction.
  • Altres:

    Autor segons l'article: Pan Z; Loiko P; Slimi S; Yuan H; Wang Y; Zhao Y; Camy P; Dunina E; Kornienko A; Fomicheva L; Wang L; Chen W; Griebner U; Petrov V; Solé RM; Díaz F; Aguiló M; Mateos X
    Departament: Química Física i Inorgànica
    Autor/s de la URV: Aguiló Díaz, Magdalena / Díaz González, Francisco Manuel / Mateos Ferré, Xavier / Slimi, Sami / Solé Cartañà, Rosa Maria
    Paraules clau: Thin-disk laser Structure refinement Raman spectra Optical absorption Judd-ofelt theory Czochralski growth Aluminate crystals ybcagdalo4 laser transitions structure refinement srlaalo4 spectroscopy raman spectra optical absorption mode judd-ofelt theory ions intensities energy-levels czochralski growth configuration-interaction
    Resum: “Mixed” calcium rare-earth aluminate laser host crystals Ca(Gd,Lu)AlO4 (CALGLO) with up to 10.8 at.% Lu codoped with Tm3+ and Ho3+ ions are grown by the Czochralski method along the [001] direction. The segregation of rare-earth ions is studied. The crystal structure is refined by the Rietveld method. Tm,Ho:Ca(Gd,Lu)AlO4 crystallizes in the tetragonal system (sp. gr. I4/mmm) exhibiting a K2NiF4 type structure. The lattice constants are a = 3.6585(6) Å and c = 11.9660(9) Å for a crystal with a composition of CaGd0.8947Lu0.0551Tm0.0448Ho0.0054AlO4. The stability of Ca(Gd,Lu)AlO4 solid-solutions is discussed. The polarized Raman spectra are measured, revealing a most intense mode at 311 cm−1 and a maximum phonon frequency of ∼650 cm−1. The polarized absorption spectra are measured. The transition intensities for the Ho3+ ion are analyzed using the modified Judd-Ofelt theory accounting for configuration interaction.
    Àrees temàtiques: Química Optics Odontología Medicina ii Medicina i Materiais Interdisciplinar General chemistry Farmacia Ensino Engenharias iv Engenharias iii Engenharias ii Condensed matter physics Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciência de alimentos Chemistry (miscellaneous) Chemistry (all) Biotecnología Biophysics Biochemistry Atomic and molecular physics, and optics Astronomia / física
    Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
    Adreça de correu electrònic de l'autor: sami.slimi@estudiants.urv.cat sami.slimi@estudiants.urv.cat magdalena.aguilo@urv.cat rosam.sole@urv.cat xavier.mateos@urv.cat f.diaz@urv.cat
    Identificador de l'autor: 0000-0001-6130-9579 0000-0002-5769-4141 0000-0003-1940-1990 0000-0003-4581-4967
    Data d'alta del registre: 2024-09-07
    Versió de l'article dipositat: info:eu-repo/semantics/publishedVersion
    Enllaç font original: https://www.sciencedirect.com/science/article/pii/S002223132200103X
    URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referència a l'article segons font original: Journal Of Luminescence. 246
    Referència de l'ítem segons les normes APA: Pan Z; Loiko P; Slimi S; Yuan H; Wang Y; Zhao Y; Camy P; Dunina E; Kornienko A; Fomicheva L; Wang L; Chen W; Griebner U; Petrov V; Solé RM; Díaz F; Ag (2022). Tm,Ho:Ca(Gd,Lu)AlO4 crystals: Crystal growth, structure refinement and Judd-Ofelt analysis. Journal Of Luminescence, 246(), -. DOI: 10.1016/j.jlumin.2022.118828
    DOI de l'article: 10.1016/j.jlumin.2022.118828
    Entitat: Universitat Rovira i Virgili
    Any de publicació de la revista: 2022
    Tipus de publicació: Journal Publications
  • Paraules clau:

    Atomic and Molecular Physics, and Optics,Biochemistry,Biophysics,Chemistry (Miscellaneous),Condensed Matter Physics,Optics
    Thin-disk laser
    Structure refinement
    Raman spectra
    Optical absorption
    Judd-ofelt theory
    Czochralski growth
    Aluminate crystals
    ybcagdalo4 laser
    transitions
    structure refinement
    srlaalo4
    spectroscopy
    raman spectra
    optical absorption
    mode
    judd-ofelt theory
    ions
    intensities
    energy-levels
    czochralski growth
    configuration-interaction
    Química
    Optics
    Odontología
    Medicina ii
    Medicina i
    Materiais
    Interdisciplinar
    General chemistry
    Farmacia
    Ensino
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Condensed matter physics
    Ciências biológicas ii
    Ciências biológicas i
    Ciências ambientais
    Ciência de alimentos
    Chemistry (miscellaneous)
    Chemistry (all)
    Biotecnología
    Biophysics
    Biochemistry
    Atomic and molecular physics, and optics
    Astronomia / física
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