Autor segons l'article: Pan, Zhongben; Loiko, Pavel; Slimi, Sami; Yuan, Hualei; Wang, Yicheng; Zhao, Yongguang; Camy, Patrice; Dunina, Elena; Kornienko, Alexey; Fomicheva, Liudmila; Wang, Li; Chen, Weidong; Griebner, Uwe; Petrov, Valentin; Sole, Rosa Maria; Diaz, Francesc; Aguilo, Magdalena; Mateos, Xavier
Departament: Química Física i Inorgànica
Autor/s de la URV: Aguiló Díaz, Magdalena / Díaz González, Francisco Manuel / Mateos Ferré, Xavier / Slimi, Sami / Solé Cartañà, Rosa Maria
Paraules clau: Thin-disk laser; Structure refinement; Raman spectra; Optical absorption; Judd-ofelt theory; Czochralski growth; Aluminate crystals; ybcagdalo4 laser; transitions; structure refinement; srlaalo4; spectroscopy; raman spectra; optical absorption; mode; judd-ofelt theory; ions; intensities; energy-levels; czochralski growth; configuration-interaction
Resum: “Mixed” calcium rare-earth aluminate laser host crystals Ca(Gd,Lu)AlO4 (CALGLO) with up to 10.8 at.% Lu codoped with Tm3+ and Ho3+ ions are grown by the Czochralski method along the [001] direction. The segregation of rare-earth ions is studied. The crystal structure is refined by the Rietveld method. Tm,Ho:Ca(Gd,Lu)AlO4 crystallizes in the tetragonal system (sp. gr. I4/mmm) exhibiting a K2NiF4 type structure. The lattice constants are a = 3.6585(6) Å and c = 11.9660(9) Å for a crystal with a composition of CaGd0.8947Lu0.0551Tm0.0448Ho0.0054AlO4. The stability of Ca(Gd,Lu)AlO4 solid-solutions is discussed. The polarized Raman spectra are measured, revealing a most intense mode at 311 cm−1 and a maximum phonon frequency of ∼650 cm−1. The polarized absorption spectra are measured. The transition intensities for the Ho3+ ion are analyzed using the modified Judd-Ofelt theory accounting for configuration interaction.
Àrees temàtiques: Química; Optics; Odontología; Medicina ii; Medicina i; Materiais; Interdisciplinar; General chemistry; Farmacia; Ensino; Engenharias iv; Engenharias iii; Engenharias ii; Condensed matter physics; Ciências biológicas ii; Ciências biológicas i; Ciências ambientais; Ciência de alimentos; Chemistry (miscellaneous); Chemistry (all); Biotecnología; Biophysics; Biochemistry; Atomic and molecular physics, and optics; Astronomia / física
Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
Adreça de correu electrònic de l'autor: sami.slimi@estudiants.urv.cat; sami.slimi@estudiants.urv.cat; magdalena.aguilo@urv.cat; rosam.sole@urv.cat; xavier.mateos@urv.cat; f.diaz@urv.cat
Data d'alta del registre: 2025-03-15
Versió de l'article dipositat: info:eu-repo/semantics/publishedVersion
Enllaç font original: https://www.sciencedirect.com/science/article/pii/S002223132200103X
URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
Referència a l'article segons font original: Journal Of Luminescence. 246 118828-
Referència de l'ítem segons les normes APA: Pan, Zhongben; Loiko, Pavel; Slimi, Sami; Yuan, Hualei; Wang, Yicheng; Zhao, Yongguang; Camy, Patrice; Dunina, Elena; Kornienko, Alexey; Fomicheva, Li (2022). Tm,Ho:Ca(Gd,Lu)AlO4 crystals: Crystal growth, structure refinement and Judd-Ofelt analysis. Journal Of Luminescence, 246(), 118828-. DOI: 10.1016/j.jlumin.2022.118828
DOI de l'article: 10.1016/j.jlumin.2022.118828
Entitat: Universitat Rovira i Virgili
Any de publicació de la revista: 2022
Tipus de publicació: Journal Publications
Repositori URV