Autor segons l'article: Pan Z; Loiko P; Slimi S; Yuan H; Wang Y; Zhao Y; Camy P; Dunina E; Kornienko A; Fomicheva L; Wang L; Chen W; Griebner U; Petrov V; Solé RM; Díaz F; Aguiló M; Mateos X
Departament: Química Física i Inorgànica
Autor/s de la URV: Aguiló Díaz, Magdalena / Díaz González, Francisco Manuel / Mateos Ferré, Xavier / Slimi, Sami / Solé Cartañà, Rosa Maria
Paraules clau: Thin-disk laser Structure refinement Raman spectra Optical absorption Judd-ofelt theory Czochralski growth Aluminate crystals ybcagdalo4 laser transitions structure refinement srlaalo4 spectroscopy raman spectra optical absorption mode judd-ofelt theory ions intensities energy-levels czochralski growth configuration-interaction
Resum: “Mixed” calcium rare-earth aluminate laser host crystals Ca(Gd,Lu)AlO4 (CALGLO) with up to 10.8 at.% Lu codoped with Tm3+ and Ho3+ ions are grown by the Czochralski method along the [001] direction. The segregation of rare-earth ions is studied. The crystal structure is refined by the Rietveld method. Tm,Ho:Ca(Gd,Lu)AlO4 crystallizes in the tetragonal system (sp. gr. I4/mmm) exhibiting a K2NiF4 type structure. The lattice constants are a = 3.6585(6) Å and c = 11.9660(9) Å for a crystal with a composition of CaGd0.8947Lu0.0551Tm0.0448Ho0.0054AlO4. The stability of Ca(Gd,Lu)AlO4 solid-solutions is discussed. The polarized Raman spectra are measured, revealing a most intense mode at 311 cm−1 and a maximum phonon frequency of ∼650 cm−1. The polarized absorption spectra are measured. The transition intensities for the Ho3+ ion are analyzed using the modified Judd-Ofelt theory accounting for configuration interaction.
Àrees temàtiques: Química Optics Odontología Medicina ii Medicina i Materiais Interdisciplinar General chemistry Farmacia Ensino Engenharias iv Engenharias iii Engenharias ii Condensed matter physics Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciência de alimentos Chemistry (miscellaneous) Chemistry (all) Biotecnología Biophysics Biochemistry Atomic and molecular physics, and optics Astronomia / física
Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
Adreça de correu electrònic de l'autor: sami.slimi@estudiants.urv.cat sami.slimi@estudiants.urv.cat magdalena.aguilo@urv.cat rosam.sole@urv.cat xavier.mateos@urv.cat f.diaz@urv.cat
Identificador de l'autor: 0000-0001-6130-9579 0000-0002-5769-4141 0000-0003-1940-1990 0000-0003-4581-4967
Data d'alta del registre: 2024-09-07
Versió de l'article dipositat: info:eu-repo/semantics/publishedVersion
URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
Referència a l'article segons font original: Journal Of Luminescence. 246
Referència de l'ítem segons les normes APA: Pan Z; Loiko P; Slimi S; Yuan H; Wang Y; Zhao Y; Camy P; Dunina E; Kornienko A; Fomicheva L; Wang L; Chen W; Griebner U; Petrov V; Solé RM; Díaz F; Ag (2022). Tm,Ho:Ca(Gd,Lu)AlO4 crystals: Crystal growth, structure refinement and Judd-Ofelt analysis. Journal Of Luminescence, 246(), -. DOI: 10.1016/j.jlumin.2022.118828
Entitat: Universitat Rovira i Virgili
Any de publicació de la revista: 2022
Tipus de publicació: Journal Publications
Repositori URV