Autor según el artículo: Pan Z; Loiko P; Slimi S; Yuan H; Wang Y; Zhao Y; Camy P; Dunina E; Kornienko A; Fomicheva L; Wang L; Chen W; Griebner U; Petrov V; Solé RM; Díaz F; Aguiló M; Mateos X
Departamento: Química Física i Inorgànica
Autor/es de la URV: Aguiló Díaz, Magdalena / Díaz González, Francisco Manuel / Mateos Ferré, Xavier / Slimi, Sami / Solé Cartañà, Rosa Maria
Palabras clave: Thin-disk laser Structure refinement Raman spectra Optical absorption Judd-ofelt theory Czochralski growth Aluminate crystals ybcagdalo4 laser transitions structure refinement srlaalo4 spectroscopy raman spectra optical absorption mode judd-ofelt theory ions intensities energy-levels czochralski growth configuration-interaction
Resumen: “Mixed” calcium rare-earth aluminate laser host crystals Ca(Gd,Lu)AlO4 (CALGLO) with up to 10.8 at.% Lu codoped with Tm3+ and Ho3+ ions are grown by the Czochralski method along the [001] direction. The segregation of rare-earth ions is studied. The crystal structure is refined by the Rietveld method. Tm,Ho:Ca(Gd,Lu)AlO4 crystallizes in the tetragonal system (sp. gr. I4/mmm) exhibiting a K2NiF4 type structure. The lattice constants are a = 3.6585(6) Å and c = 11.9660(9) Å for a crystal with a composition of CaGd0.8947Lu0.0551Tm0.0448Ho0.0054AlO4. The stability of Ca(Gd,Lu)AlO4 solid-solutions is discussed. The polarized Raman spectra are measured, revealing a most intense mode at 311 cm−1 and a maximum phonon frequency of ∼650 cm−1. The polarized absorption spectra are measured. The transition intensities for the Ho3+ ion are analyzed using the modified Judd-Ofelt theory accounting for configuration interaction.
Áreas temáticas: Química Optics Odontología Medicina ii Medicina i Materiais Interdisciplinar General chemistry Farmacia Ensino Engenharias iv Engenharias iii Engenharias ii Condensed matter physics Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciência de alimentos Chemistry (miscellaneous) Chemistry (all) Biotecnología Biophysics Biochemistry Atomic and molecular physics, and optics Astronomia / física
Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
Direcció de correo del autor: sami.slimi@estudiants.urv.cat sami.slimi@estudiants.urv.cat magdalena.aguilo@urv.cat rosam.sole@urv.cat xavier.mateos@urv.cat f.diaz@urv.cat
Identificador del autor: 0000-0001-6130-9579 0000-0002-5769-4141 0000-0003-1940-1990 0000-0003-4581-4967
Fecha de alta del registro: 2024-09-07
Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
Enlace a la fuente original: https://www.sciencedirect.com/science/article/pii/S002223132200103X
URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
Referencia al articulo segun fuente origial: Journal Of Luminescence. 246
Referencia de l'ítem segons les normes APA: Pan Z; Loiko P; Slimi S; Yuan H; Wang Y; Zhao Y; Camy P; Dunina E; Kornienko A; Fomicheva L; Wang L; Chen W; Griebner U; Petrov V; Solé RM; Díaz F; Ag (2022). Tm,Ho:Ca(Gd,Lu)AlO4 crystals: Crystal growth, structure refinement and Judd-Ofelt analysis. Journal Of Luminescence, 246(), -. DOI: 10.1016/j.jlumin.2022.118828
DOI del artículo: 10.1016/j.jlumin.2022.118828
Entidad: Universitat Rovira i Virgili
Año de publicación de la revista: 2022
Tipo de publicación: Journal Publications
Repositori URV