Autor segons l'article: Masdeu-Bulto, Anna M; Reguero, Mar; Claver, Carmen
Departament: Química Física i Inorgànica
Autor/s de la URV: Claver Cabrero, Maria del Carmen Orosia / Masdeu Bultó, Anna Maria / Reguero de la Poza, Maria del Mar
Paraules clau: Selective photochemical reduction Reaction mechanisms Photocatalysis Molecular catalysts Density functional calculations Carbon dioxide reduction visible-light reaction mechanisms photocatalysis nickel(ii) complexes molecular catalysts molecular catalyst metal-complexes light photoredox catalysis highly efficient electrochemical reduction density functional calculations conversion carbon-dioxide reduction
Resum: To stop the global warming, a complementary alternative to the decrease of CO2 production is the reduction of its amount in the atmosphere by capture and transformation into consumer products. One of the most interesting primary products is CO, used to synthesise liquid fuels. Perhaps the most attractive way of reducing CO2 to CO is the photocatalytic route. To know the details of the mechanism of this reaction can help in the design of more efficient catalytic systems. In this review, we compile the studies, undertaken from both computational and experimental approaches, of the reaction mechanism of the photoreduction of CO2 to CO by molecular catalytic systems based on transition metal complexes. The combination of experimental and computational studies can be crucial to achieve the goal aimed.
Àrees temàtiques: Química Medicina i Materiais Interdisciplinar Inorganic chemistry Farmacia Engenharias iii Engenharias ii Ciências biológicas ii Ciências biológicas i Chemistry, inorganic & nuclear Astronomia / física
Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
Adreça de correu electrònic de l'autor: annamaria.masdeu@urv.cat carmen.claver@urv.cat mar.reguero@urv.cat
Identificador de l'autor: 0000-0001-7938-3902 0000-0002-2518-7401 0000-0001-9668-8265
Data d'alta del registre: 2024-10-12
Versió de l'article dipositat: info:eu-repo/semantics/publishedVersion
Enllaç font original: https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/ejic.202100975
URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
Referència a l'article segons font original: European Journal Of Inorganic Chemistry. 2022 (14): e202100975-
Referència de l'ítem segons les normes APA: Masdeu-Bulto, Anna M; Reguero, Mar; Claver, Carmen (2022). Mechanistic Insights of Photocatalytic CO2 Reduction: Experimental versus Computational Studies. European Journal Of Inorganic Chemistry, 2022(14), e202100975-. DOI: 10.1002/ejic.202100975
DOI de l'article: 10.1002/ejic.202100975
Entitat: Universitat Rovira i Virgili
Any de publicació de la revista: 2022
Tipus de publicació: Journal Publications
Repositori URV