Articles producció científica> Química Analítica i Química Orgànica

Reductive Elimination from Sterically Encumbered Ni-Polypyridine Complexes

  • Dades identificatives

    Identificador: imarina:9282173
    Autors:
    Day, Craig S.Ton, Stephanie J.McGuire, Ryan T.Foroutan-Nejad, CinaMartin, Ruben
    Resum:
    Herein we disclose the synthesis of sterically encumbered dialkylnickel(II) complexes bearing 2,9-dimethyl-1,10phenanthroline ligands. A comparison with their unsubstituted analogues by both X-ray crystallography and theoretical calculations revealed significant distortions in their molecular structures. Eyring plots along with stoichiometric and photoexcitation studies revealed that sterically encumbered dialkylnickel(II) complexes enable facile C(sp3)-C(sp3) reductive elimination, thus offering an improved understanding of Ni catalysis.
  • Altres:

    Autor segons l'article: Day, Craig S.; Ton, Stephanie J.; McGuire, Ryan T.; Foroutan-Nejad, Cina; Martin, Ruben;
    Departament: Química Analítica i Química Orgànica
    Autor/s de la URV: Day, Craig
    Paraules clau: Remote Organo(dipyridyl)nickel complexes Nickel bonds Mild Ligand Dialkyl(dipyridyl)nickel Carboxylation Arylation Alkyl bromides Activation
    Resum: Herein we disclose the synthesis of sterically encumbered dialkylnickel(II) complexes bearing 2,9-dimethyl-1,10phenanthroline ligands. A comparison with their unsubstituted analogues by both X-ray crystallography and theoretical calculations revealed significant distortions in their molecular structures. Eyring plots along with stoichiometric and photoexcitation studies revealed that sterically encumbered dialkylnickel(II) complexes enable facile C(sp3)-C(sp3) reductive elimination, thus offering an improved understanding of Ni catalysis.
    Àrees temàtiques: Química Physical and theoretical chemistry Organic chemistry Materiais Inorganic chemistry Engenharias ii Ciências biológicas ii Ciências agrárias i Chemistry, organic Chemistry, inorganic & nuclear Astronomia / física
    Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
    Adreça de correu electrònic de l'autor: craig.day@estudiants.urv.cat
    Identificador de l'autor: 0000-0002-6931-0280
    Data d'alta del registre: 2024-08-03
    Versió de l'article dipositat: info:eu-repo/semantics/publishedVersion
    Enllaç font original: https://pubs.acs.org/doi/10.1021/acs.organomet.2c00362
    URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referència a l'article segons font original: Organometallics. 41 (19): 2662-2667
    Referència de l'ítem segons les normes APA: Day, Craig S.; Ton, Stephanie J.; McGuire, Ryan T.; Foroutan-Nejad, Cina; Martin, Ruben; (2022). Reductive Elimination from Sterically Encumbered Ni-Polypyridine Complexes. Organometallics, 41(19), 2662-2667. DOI: 10.1021/acs.organomet.2c00362
    DOI de l'article: 10.1021/acs.organomet.2c00362
    Entitat: Universitat Rovira i Virgili
    Any de publicació de la revista: 2022
    Tipus de publicació: Journal Publications
  • Paraules clau:

    Chemistry, Inorganic & Nuclear,Chemistry, Organic,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
    Remote
    Organo(dipyridyl)nickel complexes
    Nickel bonds
    Mild
    Ligand
    Dialkyl(dipyridyl)nickel
    Carboxylation
    Arylation
    Alkyl bromides
    Activation
    Química
    Physical and theoretical chemistry
    Organic chemistry
    Materiais
    Inorganic chemistry
    Engenharias ii
    Ciências biológicas ii
    Ciências agrárias i
    Chemistry, organic
    Chemistry, inorganic & nuclear
    Astronomia / física
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