Author, as appears in the article.: Day, Craig S.; Ton, Stephanie J.; McGuire, Ryan T.; Foroutan-Nejad, Cina; Martin, Ruben;
Department: Química Analítica i Química Orgànica
URV's Author/s: Day, Craig
Keywords: Remote Organo(dipyridyl)nickel complexes Nickel bonds Mild Ligand Dialkyl(dipyridyl)nickel Carboxylation Arylation Alkyl bromides Activation
Abstract: Herein we disclose the synthesis of sterically encumbered dialkylnickel(II) complexes bearing 2,9-dimethyl-1,10phenanthroline ligands. A comparison with their unsubstituted analogues by both X-ray crystallography and theoretical calculations revealed significant distortions in their molecular structures. Eyring plots along with stoichiometric and photoexcitation studies revealed that sterically encumbered dialkylnickel(II) complexes enable facile C(sp3)-C(sp3) reductive elimination, thus offering an improved understanding of Ni catalysis.
Thematic Areas: Química Physical and theoretical chemistry Organic chemistry Materiais Inorganic chemistry Engenharias ii Ciências biológicas ii Ciências agrárias i Chemistry, organic Chemistry, inorganic & nuclear Astronomia / física
licence for use: https://creativecommons.org/licenses/by/3.0/es/
Author's mail: craig.day@estudiants.urv.cat
Author identifier: 0000-0002-6931-0280
Record's date: 2024-08-03
Papper version: info:eu-repo/semantics/publishedVersion
Link to the original source: https://pubs.acs.org/doi/10.1021/acs.organomet.2c00362
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: Organometallics. 41 (19): 2662-2667
APA: Day, Craig S.; Ton, Stephanie J.; McGuire, Ryan T.; Foroutan-Nejad, Cina; Martin, Ruben; (2022). Reductive Elimination from Sterically Encumbered Ni-Polypyridine Complexes. Organometallics, 41(19), 2662-2667. DOI: 10.1021/acs.organomet.2c00362
Article's DOI: 10.1021/acs.organomet.2c00362
Entity: Universitat Rovira i Virgili
Journal publication year: 2022
Publication Type: Journal Publications
Repositori URV