Articles producció científicaQuímica Analítica i Química Orgànica

Reductive Elimination from Sterically Encumbered Ni-Polypyridine Complexes

  • Identification data

    Identifier:  imarina:9282173
    Handle: https://hdl.handle.net/20.500.11797/imarina9282173
    Authors:  Day CS; Ton SJ; McGuire RT; Foroutan-Nejad C; Martin R
    Abstract:
    Herein we disclose the synthesis of sterically encumbered dialkylnickel(II) complexes bearing 2,9-dimethyl-1,10phenanthroline ligands. A comparison with their unsubstituted analogues by both X-ray crystallography and theoretical calculations revealed significant distortions in their molecular structures. Eyring plots along with stoichiometric and photoexcitation studies revealed that sterically encumbered dialkylnickel(II) complexes enable facile C(sp3)-C(sp3) reductive elimination, thus offering an improved understanding of Ni catalysis.

  • Others:

    Link to the original source: https://pubs.acs.org/doi/10.1021/acs.organomet.2c00362
    APA: Day CS; Ton SJ; McGuire RT; Foroutan-Nejad C; Martin R (2022). Reductive Elimination from Sterically Encumbered Ni-Polypyridine Complexes. Organometallics, 41(19), 2662-2667. DOI: 10.1021/acs.organomet.2c00362
    Paper original source: Organometallics. 41 (19): 2662-2667
    Article's DOI: 10.1021/acs.organomet.2c00362
    Journal publication year: 2022
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/publishedVersion
    Record's date: 2025-02-18
    URV's Author/s: Day, Craig
    Department: Química Analítica i Química Orgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Journal Publications
    Author, as appears in the article.: Day CS; Ton SJ; McGuire RT; Foroutan-Nejad C; Martin R
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Thematic Areas: Química, Physical and theoretical chemistry, Organic chemistry, Materiais, Inorganic chemistry, Engenharias ii, Ciências biológicas ii, Ciências agrárias i, Chemistry, organic, Chemistry, inorganic & nuclear, Astronomia / física
    Author's mail: craig.day@estudiants.urv.cat

  • Keywords:

    Remote
    Organo(dipyridyl)nickel complexes
    Nickel bonds
    Mild
    Ligand
    Dialkyl(dipyridyl)nickel
    Carboxylation
    Arylation
    Alkyl bromides
    Activation
    Chemistry
    Inorganic & Nuclear
    Organic
    Inorganic Chemistry
    Organic Chemistry
    Physical and Theoretical Chemistry
    Química
    Materiais
    Engenharias ii
    Ciências biológicas ii
    Ciências agrárias i
    Astronomia / física

  • Documents:

    DocumentPrincipal

  • Cerca a google

    Search to google scholar