Repositori URV

Autor segons l'article: Werner I; Griebel J; Masip-Sánchez A; López X; Załȩski K; Kozłowski P; Kahnt A; Boerner M; Warneke Z; Warneke J; Monakhov KY

Departament: Química Física i Inorgànica

Autor/s de la URV: López Fernández, Javier / Masip Sánchez, Albert

Paraules clau: Charge-transfer visible-light spectra polyoxometalate platforms geometry field dependence building-blocks absorption

Resum: A series of {V12}-nuclearity polyoxovanadate cages covalently functionalized with one or sandwiched by two phthalocyaninato (Pc) lanthanide (Ln) moieties via V-O-Ln bonds were prepared and fully characterized for paramagnetic Ln = SmIII-ErIII and diamagnetic Ln = LuIII, including YIII. The LnPc-functionalized {V12O32} cages with fully oxidized vanadium centers in the ground state were isolated as (nBu4N)3[HV12O32Cl(LnPc)] and (nBu4N)2[HV12O32Cl(LnPc)2] compounds. As corroborated by a combined experimental (EPR, DC and AC SQUID, laser photolysis transient absorption spectroscopy, and electrochemistry) and computational (DFT, MD, and model Hamiltonian approach) methods, the compounds feature intra- and intermolecular electron transfer that is responsible for a partial reduction at V(3d) centers from VV to VIV in the solid state and at high sample concentrations. The effects are generally Ln dependent and are clearly demonstrated for the (nBu4N)3[HV12O32Cl(LnPc)] representative with Ln = LuIII or DyIII. Intramolecular charge transfer takes place for Ln = LuIII and occurs from a Pc ligand via the Ln center to the {V12O32} core of the same molecule, whereas for Ln = DyIII, only intermolecular charge transfer is allowed, which is realized from Pc in one molecule to the {V12O32} core of another molecule usually via the nBu4N+ countercation. For all Ln but DyIII, two of these phenomena may be present in different proportions. Besides, it is demonstrated that (nBu4N)3[HV12O32Cl(DyPc)] is a field-induced single molecule magnet with a maximal relaxation time of the order 10-3 s. The obtained results open up the way to further exploration and fine-tuning of these three modular molecular nanocomposites regarding tailoring and control of their Ln-dependent charge-separated states (induced by intramolecular transfer) and relaxation dynamics as well as of electron hopping between molecules. This should enable us to realize ultra-sensitive polyoxometalate powered quasi-superconductors, sensors, and data storage/processing materials for quantum technologies and neuromorphic computing.

Àrees temàtiques: Química Physical and theoretical chemistry Medicina i Materiais Interdisciplinar Inorganic chemistry General medicine Farmacia Engenharias iii Engenharias ii Engenharias i Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências agrárias i Chemistry, inorganic & nuclear Chemistry (miscellaneous) Biotecnología Astronomia / física

Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/

Adreça de correu electrònic de l'autor: albert.masip@urv.cat javier.lopez@urv.cat

Identificador de l'autor: 0000-0003-0322-6796

Data d'alta del registre: 2024-09-07

Versió de l'article dipositat: info:eu-repo/semantics/acceptedVersion

URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/

Referència a l'article segons font original: Inorganic Chemistry. 62 (9): 3761-3775

Referència de l'ítem segons les normes APA: Werner I; Griebel J; Masip-Sánchez A; López X; Załȩski K; Kozłowski P; Kahnt A; Boerner M; Warneke Z; Warneke J; Monakhov KY (2022). Hybrid Molecular Magnets with Lanthanide- and Countercation-Mediated Interfacial Electron Transfer between Phthalocyanine and Polyoxovanadate. Inorganic Chemistry, 62(9), 3761-3775. DOI: 10.1021/acs.inorgchem.2c03599

Entitat: Universitat Rovira i Virgili

Any de publicació de la revista: 2022

Tipus de publicació: Journal Publications