Autor segons l'article: Fellah, I; Djellabi, R; Ben Amor, H; Hamdi, N; Ordonez, MF; Bianchi, CL
Departament: Enginyeria Química
Autor/s de la URV: Djellabi, Ridha
Paraules clau: Water treatment Tio -smectite 2 Solar photocatalysis Shuttle Adsorb & Hdtma modification
Resum: Slow kinetics is one of the capital issues of photocatalytic technology because of its heterogeneous nature, which involves multi-step processes. Herein, we show that the simple modification of the sol-gel-based TiO2-smectite composite by hexadecyltrimethylammonium bromide (HDTMA) significantly boosts adsorption and photocatalytic efficient sol-gel-based light towards the removal of diclofenac from water. Three photocatalysts were prepared, including TiO2, TiO2-smectite, and HDTMA-TiO2-smectite. The materials were characterized to understand the surface interaction and crystal characteristics. In terms of photoactivity, it was found that the addition of HDTMA to TiO2-smectite improved the removal rate by twice. HDTMA changes the functional groups to TiO2-smectite composite allowing enhanced adsorption and photoactivity through the so-called Adsorb and Shuttle process. The recycling tests show that HDTMA-TiO2-smectite can be used up to four times with good performance. This modification approach could intensify the removal of pollutants from water instead of using complicated and costly techniques.
Àrees temàtiques: Química Physical and theoretical chemistry Farmacia Environmental science (all) Engenharias ii Ciências biológicas ii Chemistry, physical Catalysis Astronomia / física
Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
Adreça de correu electrònic de l'autor: ridha.djellabi@urv.cat
Identificador de l'autor: 0000-0002-1475-5565
Data d'alta del registre: 2024-08-03
Versió de l'article dipositat: info:eu-repo/semantics/publishedVersion
Enllaç font original: https://www.mdpi.com/2073-4344/13/1/51
URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
Referència a l'article segons font original: Catalysts. 13 (1):
Referència de l'ítem segons les normes APA: Fellah, I; Djellabi, R; Ben Amor, H; Hamdi, N; Ordonez, MF; Bianchi, CL (2023). Enhanced Photocatalytic Kinetics Using HDTMA Coated TiO2-Smectite Composite for the Oxidation of Diclofenac under Solar Light. Catalysts, 13(1), -. DOI: 10.3390/catal13010051
DOI de l'article: 10.3390/catal13010051
Entitat: Universitat Rovira i Virgili
Any de publicació de la revista: 2023
Tipus de publicació: Journal Publications
Repositori URV