Articles producció científica> Enginyeria Química

Unlocking the Potential of Radical-mediated Photocatalysis for Lignocellulosic Biomass Conversion into Value-added Chemicals and Hydrogen: Facts, Opportunities and Challenges

  • Dades identificatives

    Identificador: imarina:9296947
    Autors:
    Aboagye, DominicDjellabi, RidhaMedina, FrancescContreras, Sandra
    Resum:
    Photocatalytic biomass conversion into high-value chemicals and fuels is considered one of the hottest ongoing research and industrial topics toward sustainable development. In short, this process can cleave Cβ-O/Cα-Cβ bonds in lignin to aromatic platform chemicals, and further conversion of the polysaccharides to other platform chemicals and H2. From the chemistry point of view, the optimization of the unique cooperative interplay of radical oxidation species (which are activated via molecular oxygen species, ROSs) and substrate-derived radical intermediates by appropriate control of their type and/or yield is key to the selective production of desired products. Technically, several challenges have been raised that face successful real-world applications. This review aims to discuss the recently reported mechanistic pathways toward selective biomass conversion through the optimization of ROSs behavior and materials/system design. On top of that, through a SWOT analysis, we critically discussed this technology from both chemistry and technological viewpoints to help the scientists and engineers bridge the gap between lab-scale and large-scale production.© 2023 Wiley-VCH GmbH.
  • Altres:

    Autor segons l'article: Aboagye, Dominic; Djellabi, Ridha; Medina, Francesc; Contreras, Sandra
    Departament: Enginyeria Química
    Autor/s de la URV: Aboagye, Dominic / Contreras Iglesias, Sandra / Djellabi, Ridha / Medina Cabello, Francisco
    Paraules clau: Value-added chemicals Radical oxygen species Photocatalysis Lignocellulose Hydrogen * photocatalysis * lignocellulose * radical oxygen species * value-added chemicals Hydrogen
    Resum: Photocatalytic biomass conversion into high-value chemicals and fuels is considered one of the hottest ongoing research and industrial topics toward sustainable development. In short, this process can cleave Cβ-O/Cα-Cβ bonds in lignin to aromatic platform chemicals, and further conversion of the polysaccharides to other platform chemicals and H2. From the chemistry point of view, the optimization of the unique cooperative interplay of radical oxidation species (which are activated via molecular oxygen species, ROSs) and substrate-derived radical intermediates by appropriate control of their type and/or yield is key to the selective production of desired products. Technically, several challenges have been raised that face successful real-world applications. This review aims to discuss the recently reported mechanistic pathways toward selective biomass conversion through the optimization of ROSs behavior and materials/system design. On top of that, through a SWOT analysis, we critically discussed this technology from both chemistry and technological viewpoints to help the scientists and engineers bridge the gap between lab-scale and large-scale production.© 2023 Wiley-VCH GmbH.
    Àrees temàtiques: Química Medicina ii Medicina i Materiais Interdisciplinar General medicine General chemistry Farmacia Engenharias ii Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Catalysis Astronomia / física
    Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
    Adreça de correu electrònic de l'autor: dominic.aboagye@estudiants.urv.cat dominic.aboagye@estudiants.urv.cat sandra.contreras@urv.cat francesc.medina@urv.cat
    Identificador de l'autor: 0000-0001-8917-4733 0000-0002-3111-1542
    Data d'alta del registre: 2024-10-12
    Versió de l'article dipositat: info:eu-repo/semantics/publishedVersion
    Enllaç font original: https://onlinelibrary.wiley.com/doi/10.1002/anie.202301909
    URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referència a l'article segons font original: Angewandte Chemie (International Ed. Print). 62 (36): e202301909-e202301909
    Referència de l'ítem segons les normes APA: Aboagye, Dominic; Djellabi, Ridha; Medina, Francesc; Contreras, Sandra (2023). Unlocking the Potential of Radical-mediated Photocatalysis for Lignocellulosic Biomass Conversion into Value-added Chemicals and Hydrogen: Facts, Opportunities and Challenges. Angewandte Chemie (International Ed. Print), 62(36), e202301909-e202301909. DOI: 10.1002/anie.202301909
    DOI de l'article: 10.1002/anie.202301909
    Entitat: Universitat Rovira i Virgili
    Any de publicació de la revista: 2023
    Tipus de publicació: Journal Publications
  • Paraules clau:

    Catalysis,Chemistry,Chemistry (Miscellaneous),Chemistry, Multidisciplinary
    Value-added chemicals
    Radical oxygen species
    Photocatalysis
    Lignocellulose
    Hydrogen * photocatalysis * lignocellulose * radical oxygen species * value-added chemicals
    Hydrogen
    Química
    Medicina ii
    Medicina i
    Materiais
    Interdisciplinar
    General medicine
    General chemistry
    Farmacia
    Engenharias ii
    Ciências biológicas iii
    Ciências biológicas ii
    Ciências biológicas i
    Chemistry, multidisciplinary
    Chemistry (miscellaneous)
    Chemistry (all)
    Chemistry
    Catalysis
    Astronomia / física
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