Articles producció científica> Enginyeria Electrònica, Elèctrica i Automàtica

Fabrication of Au-Decorated Al Nanoconcavities Platform for Augmented SERS

  • Dades identificatives

    Identificador: imarina:9330076
    Autors:
    Dar, Gohar IjazXifre-Perez, ElisabetMarsal, Lluis F
    Resum:
    A robust and competitive technology to synthesize arranged high-density gold nanoparticles on highly uniform Al nanoconcavities substrates is presented. The nanoparticles are formed through sputtering and thermal annealing treatment on Al templates, which are synthesized through particular removal of nanoporous anodic alumina structure with controlled anodization conditions and with phosphoric acid as electrolyte. This scalable fabrication mechanism regulates the particle size, arrangement, shape and interparticle separation across large surface areas, which empowers the optimization of their surface enhanced Raman scattering (SERS) activities. 4-mercaptopyridine is selected as a probe molecule. Analysis reveals that Au-decorated Al nanoconcavities substrates are highly competitive for the enhancement of Raman signals and could be employed as self-sustaining nanosensors. By using these templates, a concentration as low as 10−7 M of 4-mercaptopyridine is easily detected. Finally, the calculated EF factor of 1.1 × 107 confirms the suitability for effective and sensitive SERS detection of the developed substrates.
  • Altres:

    Autor segons l'article: Dar, Gohar Ijaz; Xifre-Perez, Elisabet; Marsal, Lluis F
    Departament: Enginyeria Electrònica, Elèctrica i Automàtica
    Autor/s de la URV: Dar, Gohar Ijaz / Marsal Garví, Luis Francisco / Xifré Pérez, Elisabet
    Codi de projecte: Grant agreement No. 945413
    Paraules clau: Surface enhanced raman spectroscopy Nanoporous anodic alumina Magnetron sputtering Aluminum nanoconcavities 4-mercaptopyridine surface enhanced raman spectroscopy rugate filters real-time performance magnetron sputtering lspr gold nanoparticles enhanced raman-scattering aluminum nanoconcavities
    Resum: A robust and competitive technology to synthesize arranged high-density gold nanoparticles on highly uniform Al nanoconcavities substrates is presented. The nanoparticles are formed through sputtering and thermal annealing treatment on Al templates, which are synthesized through particular removal of nanoporous anodic alumina structure with controlled anodization conditions and with phosphoric acid as electrolyte. This scalable fabrication mechanism regulates the particle size, arrangement, shape and interparticle separation across large surface areas, which empowers the optimization of their surface enhanced Raman scattering (SERS) activities. 4-mercaptopyridine is selected as a probe molecule. Analysis reveals that Au-decorated Al nanoconcavities substrates are highly competitive for the enhancement of Raman signals and could be employed as self-sustaining nanosensors. By using these templates, a concentration as low as 10−7 M of 4-mercaptopyridine is easily detected. Finally, the calculated EF factor of 1.1 × 107 confirms the suitability for effective and sensitive SERS detection of the developed substrates.
    Àrees temàtiques: Química Mechanics of materials Mechanical engineering Materials science, multidisciplinary Materiais Interdisciplinar Chemistry, multidisciplinary Astronomia / física
    Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
    Adreça de correu electrònic de l'autor: goharijaz.dar@urv.cat goharijaz.dar@urv.cat elisabet.xifre@urv.cat lluis.marsal@urv.cat
    Identificador de l'autor: 0000-0001-6072-9889 0000-0002-5976-1408
    Data d'alta del registre: 2024-10-12
    Versió de l'article dipositat: info:eu-repo/semantics/publishedVersion
    Enllaç font original: https://onlinelibrary.wiley.com/doi/10.1002/admi.202300560
    Programa de finançament: Marie Sklodowska-Curie Actions – European Union’s Horizon 2020 research and innovation programme
    URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referència a l'article segons font original: Advanced Materials Interfaces. 10 (35):
    Referència de l'ítem segons les normes APA: Dar, Gohar Ijaz; Xifre-Perez, Elisabet; Marsal, Lluis F (2023). Fabrication of Au-Decorated Al Nanoconcavities Platform for Augmented SERS. Advanced Materials Interfaces, 10(35), -. DOI: 10.1002/admi.202300560
    Acrònim: MFP-Plus
    DOI de l'article: 10.1002/admi.202300560
    Entitat: Universitat Rovira i Virgili
    Any de publicació de la revista: 2023
    Acció del programa de finançament: Martí i Franquès COFUND Doctoral Programme
    Tipus de publicació: Journal Publications
  • Paraules clau:

    Chemistry, Multidisciplinary,Materials Science, Multidisciplinary,Mechanical Engineering,Mechanics of Materials
    Surface enhanced raman spectroscopy
    Nanoporous anodic alumina
    Magnetron sputtering
    Aluminum nanoconcavities
    4-mercaptopyridine
    surface enhanced raman spectroscopy
    rugate filters
    real-time
    performance
    magnetron sputtering
    lspr
    gold nanoparticles
    enhanced raman-scattering
    aluminum nanoconcavities
    Química
    Mechanics of materials
    Mechanical engineering
    Materials science, multidisciplinary
    Materiais
    Interdisciplinar
    Chemistry, multidisciplinary
    Astronomia / física
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