Autor según el artículo: Dar, Gohar Ijaz; Xifre-Perez, Elisabet; Marsal, Lluis F
Departamento: Enginyeria Electrònica, Elèctrica i Automàtica
Autor/es de la URV: Dar, Gohar Ijaz / Marsal Garví, Luis Francisco / Xifré Pérez, Elisabet
Código de proyecto: Grant agreement No. 945413
Palabras clave: Surface enhanced raman spectroscopy Nanoporous anodic alumina Magnetron sputtering Aluminum nanoconcavities 4-mercaptopyridine surface enhanced raman spectroscopy rugate filters real-time performance magnetron sputtering lspr gold nanoparticles enhanced raman-scattering aluminum nanoconcavities
Resumen: A robust and competitive technology to synthesize arranged high-density gold nanoparticles on highly uniform Al nanoconcavities substrates is presented. The nanoparticles are formed through sputtering and thermal annealing treatment on Al templates, which are synthesized through particular removal of nanoporous anodic alumina structure with controlled anodization conditions and with phosphoric acid as electrolyte. This scalable fabrication mechanism regulates the particle size, arrangement, shape and interparticle separation across large surface areas, which empowers the optimization of their surface enhanced Raman scattering (SERS) activities. 4-mercaptopyridine is selected as a probe molecule. Analysis reveals that Au-decorated Al nanoconcavities substrates are highly competitive for the enhancement of Raman signals and could be employed as self-sustaining nanosensors. By using these templates, a concentration as low as 10−7 M of 4-mercaptopyridine is easily detected. Finally, the calculated EF factor of 1.1 × 107 confirms the suitability for effective and sensitive SERS detection of the developed substrates.
Áreas temáticas: Química Mechanics of materials Mechanical engineering Materials science, multidisciplinary Materiais Interdisciplinar Chemistry, multidisciplinary Astronomia / física
Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
Direcció de correo del autor: goharijaz.dar@urv.cat goharijaz.dar@urv.cat elisabet.xifre@urv.cat lluis.marsal@urv.cat
Identificador del autor: 0000-0001-6072-9889 0000-0002-5976-1408
Fecha de alta del registro: 2024-10-12
Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
Programa de financiación: Marie Sklodowska-Curie Actions – European Union’s Horizon 2020 research and innovation programme
URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
Referencia al articulo segun fuente origial: Advanced Materials Interfaces. 10 (35):
Referencia de l'ítem segons les normes APA: Dar, Gohar Ijaz; Xifre-Perez, Elisabet; Marsal, Lluis F (2023). Fabrication of Au-Decorated Al Nanoconcavities Platform for Augmented SERS. Advanced Materials Interfaces, 10(35), -. DOI: 10.1002/admi.202300560
Acrónimo: MFP-Plus
Entidad: Universitat Rovira i Virgili
Año de publicación de la revista: 2023
Acción del progama de financiación: Martí i Franquès COFUND Doctoral Programme
Tipo de publicación: Journal Publications