Author, as appears in the article.: Sergio Castillón Yolanda Díaz Omar Boutureira M. Isabel Matheu
Department: Química Analítica i Química Orgànica
URV's Author/s: Sergio Castillón Yolanda Díaz Omar Boutureira MATHEU MALPARTIDA, MARÍA ISABEL
Keywords: cross metathesis
Abstract: 2,3-Dideoxy-D-ribopyranose units are important ring systems found in nature. Herein, we develop a metal-mediated strategy to form this important scaffold featuring a cross-metathesis reaction of the corresponding sugar-derived hydroxyalkene with electron-rich phenyl vinyl sulfide using commercially available ruthenium-catalysts under microwave irradiation as a key step. The final 2,3-dideoxyhexopyranose ring is generated in a single step upon 6-endo electrophilic cyclization.
Research group: Síntesis Orgànica Estereoselectiva
Thematic Areas: Chemistry Química Química
licence for use: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 2046-2069
Author identifier: n/a 0000-0001-5567-8108 0000-0002-0768-8309 0000-0001-5216-9260
Record's date: 2015-04-16
Last page: 19799
Papper version: info:eu-repo/semantics/acceptedVersion
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Entity: Universitat Rovira i Virgili
Journal publication year: 2014
First page: 19794
Publication Type: Article Artículo Article
Repositori URV