Author, as appears in the article.: Sanz, X.; Vogels, C.M.; Decken, A.; Bo, C.; Westcott, S.A.; Fernández, E.
Department: Química Física i Inorgànica
URV's Author/s: SANZ LÓPEZ, XAVIER; Vogels, C.M.; Decken, A.; BO JANÉ, CARLES; Westcott, S.A.; FERNÁNDEZ GUTIÉRREZ, MARIA ELENA
Keywords: borane
Abstract: Activated olefins directly react with phenylselenium boranes, at room temperature, without the need of metal or organocatalytic assistance. A simple mechanism that involves the interaction of the electron pair of carbonyl functional group in ¿,¿-unsaturated ketones and aldehydes, with the empty p orbital of the boron atom, justifies the efficient reaction towards the kinetically and thermodynamically most stable 1,4-addition product. Up to 12 examples of ¿ (phenylseleno) substituted ketones and aldehydes have been prepared with moderate to high yield. The simplicity and efficiency of this new reactivity generates new strategic platforms towards the C-Se bond formation and opens non existing pathways to create C-heteroatom bonds, as a general tool
Research group: Organometàl.lics i Catàlisi Homogènia
Thematic Areas: Química Química Chemistry
licence for use: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 1359-7345
Author identifier: n/a; n/a; n/a; 0000-0001-9581-2922; n/a; 0000-0001-9025-1791
Record's date: 2017-03-16
Last page: 8423
Journal volume: 50
Papper version: info:eu-repo/semantics/acceptedVersion
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Entity: Universitat Rovira i Virgili
Journal publication year: 2014
First page: 8420
Publication Type: Article Artículo Article
Repositori URV