Articles producció científica> Química Física i Inorgànica

Face to face activation of phenylselenium boranes with α,β-unsaturated carbonyl substrates: facile synthesis of C-Se bonds

  • Identification data

    Identifier: PC:2633
    Authors:
    Sanz, X.Vogels, C.M.Decken, A.Bo, C.Westcott, S.A.Fernández, E.
    Abstract:
    author can archive pre-print (ie pre-refereeing). 12 meses de embargo DOI: 10.1039/c4cc02098g URL: http://pubs.rsc.org/en/Content/ArticleLanding/2014/CC/c4cc02098g#!divAbstract Filiació URV: SI
  • Others:

    Author, as appears in the article.: Sanz, X.; Vogels, C.M.; Decken, A.; Bo, C.; Westcott, S.A.; Fernández, E.
    Department: Química Física i Inorgànica
    URV's Author/s: SANZ LÓPEZ, XAVIER; Vogels, C.M.; Decken, A.; BO JANÉ, CARLES; Westcott, S.A.; FERNÁNDEZ GUTIÉRREZ, MARIA ELENA
    Keywords: borane
    Abstract: Activated olefins directly react with phenylselenium boranes, at room temperature, without the need of metal or organocatalytic assistance. A simple mechanism that involves the interaction of the electron pair of carbonyl functional group in ¿,¿-unsaturated ketones and aldehydes, with the empty p orbital of the boron atom, justifies the efficient reaction towards the kinetically and thermodynamically most stable 1,4-addition product. Up to 12 examples of ¿ (phenylseleno) substituted ketones and aldehydes have been prepared with moderate to high yield. The simplicity and efficiency of this new reactivity generates new strategic platforms towards the C-Se bond formation and opens non existing pathways to create C-heteroatom bonds, as a general tool
    Research group: Organometàl.lics i Catàlisi Homogènia
    Thematic Areas: Química Química Chemistry
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 1359-7345
    Author identifier: n/a; n/a; n/a; 0000-0001-9581-2922; n/a; 0000-0001-9025-1791
    Record's date: 2017-03-16
    Last page: 8423
    Journal volume: 50
    Papper version: info:eu-repo/semantics/acceptedVersion
    Link to the original source: https://pubs.rsc.org/en/content/articlelanding/2014/CC/c4cc02098g#!divAbstract
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Article's DOI: 10.1039/c4cc02098g
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2014
    First page: 8420
    Publication Type: Article Artículo Article
  • Keywords:

    Borans -- Síntesi
    borane
    Química
    Química
    Chemistry
    1359-7345
  • Documents:

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