Author, as appears in the article.: Rodríguez, A. ; Castro, E. ; Azmani, K. ; Hernandez, A. ; Aghabali, A. ; Liu, S. ; Metta-Magana, A. ; Olmstead, M. ; Poblet, J. M.; Echegoyen, L.
Department: Química Física i Inorgànica
URV's Author/s: RODRÍGUEZ FORTEA, ANTONIO; Castro, E. ; Azmani, K. ; Hernandez, A. ; Aghabali, A. ; Liu, S. ; Metta-Magana, A. ; Olmstead, M. ; POBLET RIUS, JOSEP MARIA; Echegoyen, L.
Keywords: fullerenes hexa-adducts trans-1
Abstract: A totally unanticipated regio- and stereo-isomerically pure C2h-symmetric trans-1-(bis-pyrrolidine)-tetra-malonate hexa-adduct of C60 was obtained via a topologically controlled method, followed by a 1,3-dipolar cycloaddition reaction. The structures of the products were elucidated by 1H- and 13C-NMR and by X-ray crystallography. The unexpected regio- and stereo-selectivity supported by theoretical calculations, was found to be mediated by the malonate-pyrrolidine interaction.
Research group: Química Quàntica
Thematic Areas: Química Química Chemistry
licence for use: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 0947-6539
Author identifier: 0000-0001-5884-5629; ; ; ; ; ; ; ; 0000-0002-4533-0623;
Record's date: 2018-03-01
Last page: 15944
Journal volume: 63
Papper version: info:eu-repo/semantics/acceptedVersion
Link to the original source: http://pubs.rsc.org/en/Content/ArticleLanding/2017/DT/C7DT03520A#!divAbstract
Funding program: plan; Excelencia; CTQ2014-52774-P altres; Grupos Consolidados; 2014SGR199 altres; ICREA Academia; ICREA Academia
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Article's DOI: 10.1039/c7dt03520a
Entity: Universitat Rovira i Virgili
Journal publication year: 2017
First page: 15937
Publication Type: Article Artículo Article
Repositori URV