Articles producció científicaQuímica Física i Inorgànica

Unusual C-2h-Symmetric trans-1-(Bis-pyrrolidine)-tetra-malonate Hexa-Adducts of C-60: The Unexpected Regio- and Stereocontrol Mediated by Malonate-Pyrrolidine Interaction

  • Identification data

    Identifier:  PC:3131
    Handle: https://hdl.handle.net/20.500.11797/PC3131
    Authors:  Rodríguez, A.; Castro, E.; Azmani, K.; Hernandez, A.; Aghabali, A.; Liu, S.; Metta-Magana, A.; Olmstead, M.; Poblet, J. M.; Echegoyen, L.
    Abstract:
    A totally unanticipated regio- and stereo-isomerically pure C2h-symmetric trans-1-(bis-pyrrolidine)-tetra-malonate hexa-adduct of C60 was obtained via a topologically controlled method, followed by a 1,3-dipolar cycloaddition reaction. The structures of the products were elucidated by 1H- and 13C-NMR and by X-ray crystallography. The unexpected regio- and stereo-selectivity supported by theoretical calculations, was found to be mediated by the malonate-pyrrolidine interaction.

  • Others:

    Link to the original source: http://pubs.rsc.org/en/Content/ArticleLanding/2017/DT/C7DT03520A#!divAbstract
    Article's DOI: 10.1039/c7dt03520a
    Funding program: plan; Excelencia; CTQ2014-52774-P, altres; Grupos Consolidados; 2014SGR199, altres; ICREA Academia; ICREA Academia
    Journal publication year: 2017
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/acceptedVersion
    Record's date: 2018-03-01
    First page: 15937
    URV's Author/s: RODRÍGUEZ FORTEA, ANTONIO; Castro, E. ; Azmani, K. ; Hernandez, A. ; Aghabali, A. ; Liu, S. ; Metta-Magana, A. ; Olmstead, M. ; POBLET RIUS, JOSEP MARIA; Echegoyen, L.
    Department: Química Física i Inorgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Article
    Last page: 15944
    ISSN: 0947-6539
    Author, as appears in the article.: Rodríguez, A. ; Castro, E. ; Azmani, K. ; Hernandez, A. ; Aghabali, A. ; Liu, S. ; Metta-Magana, A. ; Olmstead, M. ; Poblet, J. M.; Echegoyen, L.
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Journal volume: 63
    Research group: Química Quàntica
    Thematic Areas: Chemistry

  • Keywords:

    fullerenes
    hexa-adducts
    trans-1

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