Author, as appears in the article.: Fernández, E. ; Cuenca, A. B. ; Shishido, R. ; Ito, H.
Department: Química Física i Inorgànica
URV's Author/s: FERNÁNDEZ GUTIÉRREZ, MARIA ELENA; Cuenca, A. B. ; Shishido, R. ; Ito, H.
Keywords: Transition-metal-free B-B activation modes
Abstract: This review is a guided tour along the activation modes and reactivity of B-B, B-Si, B-N, B-S, B-Se and B-P reagents, in the absence of any transition metal complex. Here are disclosed the general concepts related to the homolytic and heterolytic cleavage of the B-B and B-interelement bonds, as well as the generation of the new C-B and C-interelement bonds, in a selective way. The greener consequences of those novel routes facilitate the gram scale preparations of target functionalised organic compounds. Intrinsic data about the suggested mechanisms and spectroscopic evidences that support the innovative theories, are provided along the review. Since this is a stimulating area of work that has emerged within the last decade, this overview serves as the basis to understand the new trends and hopefully to generate inspiration for future discoveries in the field
Research group: Organometàl.lics i Catàlisi Homogènia
Thematic Areas: Chemistry Química Química
licence for use: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 0306-0012
Author identifier: 0000-0001-9025-1791; ; ;
Record's date: 2018-03-08
Last page: 30
Journal volume: 46
Papper version: info:eu-repo/semantics/acceptedVersion
Link to the original source: http://pubs.rsc.org/en/Content/ArticleLanding/2017/CS/C6CS00692B#!divAbstract
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Article's DOI: 10.1039/c6cs00692b
Entity: Universitat Rovira i Virgili
Journal publication year: 2017
First page: 415
Publication Type: Article Artículo Article
Repositori URV