Author, as appears in the article.: Biosca M; Magre M; Pàmies O; Diéguez M
Department: Química Física i Inorgànica
URV's Author/s: Biosca Brull, Maria / Diéguez Fernández, Montserrat / Pamies Ollé, Oscar
Keywords: Unfunctionalized olefins P,n-ligands Iridium Cyclic β-enamides Cyclic ?-enamides Asymmetric hydrogenation
Abstract: © 2018 American Chemical Society. We have developed a family of Ir-P,oxazoline catalysts for asymmetric hydrogenation. These catalysts, with a simple modular architecture, have shown a high tolerance to the olefin geometry and substitution pattern, and to the presence of several neighboring polar groups. Thus, they were able to successfully hydrogenate disubstituted, trisubstituted, and tetrasubstituted minimally functionalized olefins (with enantiomeric excess values up to 99%). The excellent catalytic performance was also extended to the hydrogenation of cyclic β-enamides.
Thematic Areas: Química Materiais Interdisciplinar General chemistry Engenharias ii Ciências agrárias i Chemistry, physical Chemistry (miscellaneous) Chemistry (all) Catalysis Astronomia / física
licence for use: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 21555435
Author's mail: maria.biosca@urv.cat oscar.pamies@urv.cat montserrat.dieguez@urv.cat
Author identifier: 0000-0002-9116-6318 0000-0002-2352-8508 0000-0002-8450-0656
Last page: 10320
Record's date: 2024-09-07
Journal volume: 8
Papper version: info:eu-repo/semantics/submittedVersion
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: Acs Catalysis. 8 (11): 10316-10320
APA: Biosca M; Magre M; Pàmies O; Diéguez M (2018). Asymmetric Hydrogenation of Disubstituted, Trisubstituted, and Tetrasubstituted Minimally Functionalized Olefins and Cyclic β-Enamides with Easily Accessible Ir-P,Oxazoline Catalysts. Acs Catalysis, 8(11), 10316-10320. DOI: 10.1021/acscatal.8b03170
Entity: Universitat Rovira i Virgili
Journal publication year: 2018
First page: 10316
Publication Type: Journal Publications
Repositori URV