Autor según el artículo: Biosca M; Magre M; Pàmies O; Diéguez M
Departamento: Química Física i Inorgànica
Autor/es de la URV: Biosca Brull, Maria / Diéguez Fernández, Montserrat / Pamies Ollé, Oscar
Palabras clave: Unfunctionalized olefins P,n-ligands Iridium Cyclic β-enamides Cyclic ?-enamides Asymmetric hydrogenation
Resumen: © 2018 American Chemical Society. We have developed a family of Ir-P,oxazoline catalysts for asymmetric hydrogenation. These catalysts, with a simple modular architecture, have shown a high tolerance to the olefin geometry and substitution pattern, and to the presence of several neighboring polar groups. Thus, they were able to successfully hydrogenate disubstituted, trisubstituted, and tetrasubstituted minimally functionalized olefins (with enantiomeric excess values up to 99%). The excellent catalytic performance was also extended to the hydrogenation of cyclic β-enamides.
Áreas temáticas: Química Materiais Interdisciplinar General chemistry Engenharias ii Ciências agrárias i Chemistry, physical Chemistry (miscellaneous) Chemistry (all) Catalysis Astronomia / física
Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 21555435
Direcció de correo del autor: maria.biosca@urv.cat oscar.pamies@urv.cat montserrat.dieguez@urv.cat
Identificador del autor: 0000-0002-9116-6318 0000-0002-2352-8508 0000-0002-8450-0656
Página final: 10320
Fecha de alta del registro: 2024-09-07
Volumen de revista: 8
Versión del articulo depositado: info:eu-repo/semantics/submittedVersion
Enlace a la fuente original: https://pubs.acs.org/doi/10.1021/acscatal.8b03170
URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
Referencia al articulo segun fuente origial: Acs Catalysis. 8 (11): 10316-10320
Referencia de l'ítem segons les normes APA: Biosca M; Magre M; Pàmies O; Diéguez M (2018). Asymmetric Hydrogenation of Disubstituted, Trisubstituted, and Tetrasubstituted Minimally Functionalized Olefins and Cyclic β-Enamides with Easily Accessible Ir-P,Oxazoline Catalysts. Acs Catalysis, 8(11), 10316-10320. DOI: 10.1021/acscatal.8b03170
DOI del artículo: 10.1021/acscatal.8b03170
Entidad: Universitat Rovira i Virgili
Año de publicación de la revista: 2018
Página inicial: 10316
Tipo de publicación: Journal Publications