Autor según el artículo: Biosca M; Magre M; Pàmies O; Diéguez M

Departamento: Química Física i Inorgànica

Autor/es de la URV: Biosca Brull, Maria / Diéguez Fernández, Montserrat / Pamies Ollé, Oscar

Palabras clave: Unfunctionalized olefins P,n-ligands Iridium Cyclic β-enamides Cyclic ?-enamides Asymmetric hydrogenation

Resumen: © 2018 American Chemical Society. We have developed a family of Ir-P,oxazoline catalysts for asymmetric hydrogenation. These catalysts, with a simple modular architecture, have shown a high tolerance to the olefin geometry and substitution pattern, and to the presence of several neighboring polar groups. Thus, they were able to successfully hydrogenate disubstituted, trisubstituted, and tetrasubstituted minimally functionalized olefins (with enantiomeric excess values up to 99%). The excellent catalytic performance was also extended to the hydrogenation of cyclic β-enamides.

Áreas temáticas: Química Materiais Interdisciplinar General chemistry Engenharias ii Ciências agrárias i Chemistry, physical Chemistry (miscellaneous) Chemistry (all) Catalysis Astronomia / física

Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/

ISSN: 21555435

Direcció de correo del autor: maria.biosca@urv.cat montserrat.dieguez@urv.cat oscar.pamies@urv.cat

Identificador del autor: 0000-0002-9116-6318 0000-0002-8450-0656 0000-0002-2352-8508

Página final: 10320

Fecha de alta del registro: 2023-02-22

Volumen de revista: 8

Versión del articulo depositado: info:eu-repo/semantics/submittedVersion

Enlace a la fuente original: https://pubs.acs.org/doi/10.1021/acscatal.8b03170

URL Documento de licencia: http://repositori.urv.cat/ca/proteccio-de-dades/

Referencia al articulo segun fuente origial: Acs Catalysis. 8 (11): 10316-10320

Referencia de l'ítem segons les normes APA: Biosca M; Magre M; Pàmies O; Diéguez M (2018). Asymmetric Hydrogenation of Disubstituted, Trisubstituted, and Tetrasubstituted Minimally Functionalized Olefins and Cyclic β-Enamides with Easily Accessible Ir-P,Oxazoline Catalysts. Acs Catalysis, 8(11), 10316-10320. DOI: 10.1021/acscatal.8b03170

DOI del artículo: 10.1021/acscatal.8b03170

Entidad: Universitat Rovira i Virgili

Año de publicación de la revista: 2018

Página inicial: 10316

Tipo de publicación: Journal Publications