Author, as appears in the article.: Rodriguez-Fortea, Antonio; Kaleta, Jiri; Meziere, Cepcile; Allain, Magali; Canadell, Enric; Wzietek, Pawel; Michl, Josef; Batail, Patrick
Department: Química Física i Inorgànica
URV's Author/s: Rodríguez Fortea, Antonio
Keywords: Spin-lattice relaxation Rotors Rotation barriers
Abstract: An asymmetric mechanism for correlated motion occurring in noninteracting pairs of adjacent orthogonal 1,4-bis(carboxyethynyl)bicyclo[1.1.1]pentane (BCP) rotators 1 in the solid state is unraveled and shown to play an important role in understanding the dynamics in the crystalline rotor, Bu4N+[1-]·H2O. Single crystal X-ray diffraction and calculation of rotor-rotor interaction energies combined with variable-temperature, variable-field 1H spin-lattice relaxation experiments led to the identification and microscopic rationalization of two distinct relaxation processes.
Thematic Areas: Química Interdisciplinar General chemistry General chemical engineering Engenharias ii Ciências agrárias i Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemical engineering (miscellaneous) Chemical engineering (all)
ISSN: 24701343
Author's mail: antonio.rodriguezf@urv.cat
Author identifier: 0000-0001-5884-5629
Last page: 1297
Record's date: 2025-02-08
Journal volume: 3
Paper version: info:eu-repo/semantics/publishedVersion
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Paper original source: Acs Omega. 3 (1): 1293-1297
APA: Rodriguez-Fortea, Antonio; Kaleta, Jiri; Meziere, Cepcile; Allain, Magali; Canadell, Enric; Wzietek, Pawel; Michl, Josef; Batail, Patrick (2018). Asymmetric Choreography in Pairs of Orthogonal Rotors. Acs Omega, 3(1), 1293-1297. DOI: 10.1021/acsomega.7b01580
Entity: Universitat Rovira i Virgili
Journal publication year: 2018
First page: 1293
Publication Type: Journal Publications
Repositori URV