Articles producció científica> Química Física i Inorgànica

Asymmetric Choreography in Pairs of Orthogonal Rotors

  • Datos identificativos

    Identificador: imarina:5132289
    Handle: https://hdl.handle.net/20.500.11797/imarina5132289
    Autores:
    Rodríguez-Fortea A., Kaleta J., Meziere C., Allain M., Canadell E., Wzietek P., Michl J., Batail P.
    Resumen:
    An asymmetric mechanism for correlated motion occurring in noninteracting pairs of adjacent orthogonal 1,4-bis(carboxyethynyl)bicyclo[1.1.1]pentane (BCP) rotators 1 in the solid state is unraveled and shown to play an important role in understanding the dynamics in the crystalline rotor, Bu4N+[1-]·H2O. Single crystal X-ray diffraction and calculation of rotor-rotor interaction energies combined with variable-temperature, variable-field 1H spin-lattice relaxation experiments led to the identification and microscopic rationalization of two distinct relaxation processes.

  • Otros:

    Autor según el artículo: Rodríguez-Fortea A., Kaleta J., Meziere C., Allain M., Canadell E., Wzietek P., Michl J., Batail P.
    Departamento: Química Física i Inorgànica
    Autor/es de la URV: Rodríguez Fortea, Antonio
    Palabras clave: Spin-lattice relaxation Rotors Rotation barriers
    Resumen: An asymmetric mechanism for correlated motion occurring in noninteracting pairs of adjacent orthogonal 1,4-bis(carboxyethynyl)bicyclo[1.1.1]pentane (BCP) rotators 1 in the solid state is unraveled and shown to play an important role in understanding the dynamics in the crystalline rotor, Bu4N+[1-]·H2O. Single crystal X-ray diffraction and calculation of rotor-rotor interaction energies combined with variable-temperature, variable-field 1H spin-lattice relaxation experiments led to the identification and microscopic rationalization of two distinct relaxation processes.
    Áreas temáticas: Química Interdisciplinar General chemistry General chemical engineering Engenharias ii Ciências agrárias i Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemical engineering (miscellaneous) Chemical engineering (all)
    ISSN: 24701343
    Direcció de correo del autor: antonio.rodriguezf@urv.cat
    Identificador del autor: 0000-0001-5884-5629
    Página final: 1297
    Fecha de alta del registro: 2024-09-07
    Volumen de revista: 3
    Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
    Enlace a la fuente original: https://pubs.acs.org/doi/10.1021/acsomega.7b01580
    URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referencia al articulo segun fuente origial: Acs Omega. 3 (1): 1293-1297
    Referencia de l'ítem segons les normes APA: Rodríguez-Fortea A., Kaleta J., Meziere C., Allain M., Canadell E., Wzietek P., Michl J., Batail P. (2018). Asymmetric Choreography in Pairs of Orthogonal Rotors. Acs Omega, 3(1), 1293-1297. DOI: 10.1021/acsomega.7b01580
    DOI del artículo: 10.1021/acsomega.7b01580
    Entidad: Universitat Rovira i Virgili
    Año de publicación de la revista: 2018
    Página inicial: 1293
    Tipo de publicación: Journal Publications

  • Palabras clave:

    Chemical Engineering (Miscellaneous),Chemistry (Miscellaneous),Chemistry, Multidisciplinary
    Spin-lattice relaxation
    Rotors
    Rotation barriers
    Química
    Interdisciplinar
    General chemistry
    General chemical engineering
    Engenharias ii
    Ciências agrárias i
    Chemistry, multidisciplinary
    Chemistry (miscellaneous)
    Chemistry (all)
    Chemical engineering (miscellaneous)
    Chemical engineering (all)

  • Documentos:

    DocumentPrincipal

  • Cerca a google

    Search to google scholar