Articles producció científica> Química Analítica i Química Orgànica

Bio-based ABA triblock copolymers with central degradable moieties

  • Identification data

    Identifier: imarina:9162116
    Authors:
    Verdugo PLligadas GRonda JCGalià MCádiz V
    Abstract:
    © 2021 Elsevier Ltd A set of (poly-α-methylene-γ-butyrolactone)–co-(poly-δ-decalactone)–co-(poly-α-methylene-γ-butyrolactone) (PMBL-co-PDL-co-PMBL) ABA block copolymers containing different stimuli cleavable groups at the central point of the poly(δ-decalactone) (PDL) block were synthesized by a combination of Ring Opening Transesterification Polymerization (ROTEP) of DL, diol end-group functionalization as α-bromoester and Atom Transfer Radical Polymerization (ATRP) of α -methylene-γ-butyrolactone (MBL). Diols containing acetal, spiroacetal, thioacetal and disulphide units were used as initiators for the bulk room temperature controlled polymerization of δ-decalactone (DL) using 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) as catalyst. PDL diols were functionalized in a one-pot two-steps procedure using N-(2-bromoisobutyryl)imidazole (BiB-Im). The resulting macroinitiators were chain extended by atom transfer radical polymerization (ATRP) in DMF at 50 °C using MBL as methacrylic-like monomer and the conventional CuCl/CuCl2/2,2′-bipyridine catalyst system. The cleavage behaviour of the copolymers under reductive, acidic and photooxidative conditions has been studied and the resulting AB block copolymers structurally characterized.
  • Others:

    Author, as appears in the article.: Verdugo P; Lligadas G; Ronda JC; Galià M; Cádiz V
    Department: Química Analítica i Química Orgànica
    URV's Author/s: Cádiz Deleito, Maria Virginia / Galià Clua, Marina Teresa / Lligadas Puig, Gerard / Ronda Bargalló, Juan Carlos / Verdugo Fernandez, Pedro Manuel
    Keywords: Stimuli cleavable Rotep Renewable monomer Atrp Aba block copolymer
    Abstract: © 2021 Elsevier Ltd A set of (poly-α-methylene-γ-butyrolactone)–co-(poly-δ-decalactone)–co-(poly-α-methylene-γ-butyrolactone) (PMBL-co-PDL-co-PMBL) ABA block copolymers containing different stimuli cleavable groups at the central point of the poly(δ-decalactone) (PDL) block were synthesized by a combination of Ring Opening Transesterification Polymerization (ROTEP) of DL, diol end-group functionalization as α-bromoester and Atom Transfer Radical Polymerization (ATRP) of α -methylene-γ-butyrolactone (MBL). Diols containing acetal, spiroacetal, thioacetal and disulphide units were used as initiators for the bulk room temperature controlled polymerization of δ-decalactone (DL) using 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) as catalyst. PDL diols were functionalized in a one-pot two-steps procedure using N-(2-bromoisobutyryl)imidazole (BiB-Im). The resulting macroinitiators were chain extended by atom transfer radical polymerization (ATRP) in DMF at 50 °C using MBL as methacrylic-like monomer and the conventional CuCl/CuCl2/2,2′-bipyridine catalyst system. The cleavage behaviour of the copolymers under reductive, acidic and photooxidative conditions has been studied and the resulting AB block copolymers structurally characterized.
    Thematic Areas: Química Polymers and plastics Polymer science Physics and astronomy (miscellaneous) Physics and astronomy (all) Organic chemistry Odontología Materials chemistry Materiais Interdisciplinar General physics and astronomy Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Ciências ambientais Ciência de alimentos Ciência da computação Biotecnología Astronomia / física Arquitetura, urbanismo e design
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Author's mail: marina.galia@urv.cat juancarlos.ronda@urv.cat gerard.lligadas@urv.cat
    Author identifier: 0000-0002-4359-4510 0000-0002-0668-6600 0000-0002-8519-1840
    Record's date: 2024-11-02
    Papper version: info:eu-repo/semantics/acceptedVersion
    Link to the original source: https://www.sciencedirect.com/science/article/abs/pii/S0014305721000550
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Papper original source: European Polymer Journal. 147 (110321):
    APA: Verdugo P; Lligadas G; Ronda JC; Galià M; Cádiz V (2021). Bio-based ABA triblock copolymers with central degradable moieties. European Polymer Journal, 147(110321), -. DOI: 10.1016/j.eurpolymj.2021.110321
    Article's DOI: 10.1016/j.eurpolymj.2021.110321
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2021
    Publication Type: Journal Publications
  • Keywords:

    Materials Chemistry,Organic Chemistry,Physics and Astronomy (Miscellaneous),Polymer Science,Polymers and Plastics
    Stimuli cleavable
    Rotep
    Renewable monomer
    Atrp
    Aba block copolymer
    Química
    Polymers and plastics
    Polymer science
    Physics and astronomy (miscellaneous)
    Physics and astronomy (all)
    Organic chemistry
    Odontología
    Materials chemistry
    Materiais
    Interdisciplinar
    General physics and astronomy
    Farmacia
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Engenharias i
    Ciências ambientais
    Ciência de alimentos
    Ciência da computação
    Biotecnología
    Astronomia / física
    Arquitetura, urbanismo e design
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