Autor según el artículo: Verdugo P; Lligadas G; Ronda JC; Galià M; Cádiz V
Departamento: Química Analítica i Química Orgànica
Autor/es de la URV: Cádiz Deleito, Maria Virginia / Galià Clua, Marina Teresa / Lligadas Puig, Gerard / Ronda Bargalló, Juan Carlos
Palabras clave: Stimuli cleavable Rotep Renewable monomer Atrp Aba block copolymer
Resumen: © 2021 Elsevier Ltd A set of (poly-α-methylene-γ-butyrolactone)–co-(poly-δ-decalactone)–co-(poly-α-methylene-γ-butyrolactone) (PMBL-co-PDL-co-PMBL) ABA block copolymers containing different stimuli cleavable groups at the central point of the poly(δ-decalactone) (PDL) block were synthesized by a combination of Ring Opening Transesterification Polymerization (ROTEP) of DL, diol end-group functionalization as α-bromoester and Atom Transfer Radical Polymerization (ATRP) of α -methylene-γ-butyrolactone (MBL). Diols containing acetal, spiroacetal, thioacetal and disulphide units were used as initiators for the bulk room temperature controlled polymerization of δ-decalactone (DL) using 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) as catalyst. PDL diols were functionalized in a one-pot two-steps procedure using N-(2-bromoisobutyryl)imidazole (BiB-Im). The resulting macroinitiators were chain extended by atom transfer radical polymerization (ATRP) in DMF at 50 °C using MBL as methacrylic-like monomer and the conventional CuCl/CuCl2/2,2′-bipyridine catalyst system. The cleavage behaviour of the copolymers under reductive, acidic and photooxidative conditions has been studied and the resulting AB block copolymers structurally characterized.
Áreas temáticas: Química Polymers and plastics Polymer science Physics and astronomy (miscellaneous) Physics and astronomy (all) Organic chemistry Odontología Materials chemistry Materiais Interdisciplinar General physics and astronomy Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Ciências ambientais Ciência de alimentos Ciência da computação Biotecnología Astronomia / física Arquitetura, urbanismo e design
Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
Direcció de correo del autor: gerard.lligadas@urv.cat virginia.cadiz@urv.cat juancarlos.ronda@urv.cat marina.galia@urv.cat
Identificador del autor: 0000-0002-8519-1840 0000-0003-2689-5407 0000-0002-0668-6600 0000-0002-4359-4510
Fecha de alta del registro: 2023-02-23
Versión del articulo depositado: info:eu-repo/semantics/acceptedVersion
Enlace a la fuente original: https://www.sciencedirect.com/science/article/abs/pii/S0014305721000550
URL Documento de licencia: http://repositori.urv.cat/ca/proteccio-de-dades/
Referencia al articulo segun fuente origial: European Polymer Journal. 147 (110321):
Referencia de l'ítem segons les normes APA: Verdugo P; Lligadas G; Ronda JC; Galià M; Cádiz V (2021). Bio-based ABA triblock copolymers with central degradable moieties. European Polymer Journal, 147(110321), -. DOI: 10.1016/j.eurpolymj.2021.110321
DOI del artículo: 10.1016/j.eurpolymj.2021.110321
Entidad: Universitat Rovira i Virgili
Año de publicación de la revista: 2021
Tipo de publicación: Journal Publications
Repositori URV