Author, as appears in the article.: Pol de la Cruz Sánchez; Oscar Pàmies; Montserrat Diéguez Fernández
Department: Química Analítica i Química Orgànica
URV's Author/s: De la Cruz Sánchez Badia, Pol / Diéguez Fernández, Montserrat / Pamies Ollé, Oscar
Abstract: Asymmetric catalysis has emerged as one of the most powerful tools for the synthesis of high value organic com- pounds (i.e. pharmaceuticals, fragrances, agrochemicals, etc.). In this field, the asymmetric hydrogenation (AH) of olefins is one of the most sustainable methods due to its perfect atomic economy, high efficiency and operational simplicity. Phosphine ligands have dominated the field of asymmetric hydrogenation during the past decades, but the recent success of thioether- based ligands (developed in our group) and carbene-based ligands make these scaffolds an ideal field for further investi-gations. In this case, we decided to combine these two scaffolds with the preparation of new thioether-carbene ligands and compare their efficiency in the AH of olefins with their phosphorus-based analogues, together with mechanistic studies (reactivities with deuterium and hydrogen).
licence for use: https://creativecommons.org/licenses/by/3.0/es/
Author's mail: montserrat.dieguez@urv.cat oscar.pamies@urv.cat pol.delacruzsanchez@urv.cat
Author identifier: 0000-0002-8450-0656 0000-0002-2352-8508
Record's date: 2023-12-16
Papper version: info:eu-repo/semantics/publishedVersion
Link to the original source: https://raco.cat/index.php/RevistaSCQ/article/view/377870
Papper original source: Revista De La Societat Catalana De Química. (19): 56-71
APA: Pol de la Cruz Sánchez; Oscar Pàmies; Montserrat Diéguez Fernández (2020). Lligands tioèter-carbè N-heterocíclics per a la hidrogenació asimètrica dolefines: perspectiva i oportunitats. Revista De La Societat Catalana De Química, (19), 56-71
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Entity: Universitat Rovira i Virgili
Journal publication year: 2020
Publication Type: Journal Publications