Articles producció científica> Química Física i Inorgànica

Alkoxide activation of tetra-alkoxy diboron reagents in C-B bond formation: a decade of unpredictable reactivity

  • Identification data

    Identifier: imarina:9231292
    Authors:
    Carbo, Jorge J.Fernandez, Elena
    Abstract:
    Any attempt to facilitate a new generation of C-B bonds represents a useful tool in organic synthesis. In addition, if that approach highlights the nucleophilic character of boryl moieties in the absence of transition metal complexes, the challenge to create new reactive platforms becomes an opportunity. We have been deeply involved in the experimental and theoretical validation of C-B bond formation by means of alkoxide activation of tetra-alkoxy diboron reagents and here is presented a convenient guide to understand the concept and the applications.
  • Others:

    Author, as appears in the article.: Carbo, Jorge J.; Fernandez, Elena;
    Department: Química Física i Inorgànica
    URV's Author/s: Carbó Martin, Jorge Juan / Fernández Gutiérrez, Maria Elena
    Keywords: Tertiary Metal-free diboration Complexes Catalyst Borylation Bis(pinacolato)diboron Beta-boration Alkynes Alcohols Additions
    Abstract: Any attempt to facilitate a new generation of C-B bonds represents a useful tool in organic synthesis. In addition, if that approach highlights the nucleophilic character of boryl moieties in the absence of transition metal complexes, the challenge to create new reactive platforms becomes an opportunity. We have been deeply involved in the experimental and theoretical validation of C-B bond formation by means of alkoxide activation of tetra-alkoxy diboron reagents and here is presented a convenient guide to understand the concept and the applications.
    Thematic Areas: Surfaces, coatings and films Química Metals and alloys Medicina ii Medicina i Materials chemistry Materiais Interdisciplinar General medicine General chemistry Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Electronic, optical and magnetic materials Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Ceramics and composites Catalysis Biotecnología Biodiversidade Astronomia / física
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Author's mail: j.carbo@urv.cat mariaelena.fernandez@urv.cat
    Author identifier: 0000-0002-3945-6721 0000-0001-9025-1791
    Record's date: 2024-07-27
    Papper version: info:eu-repo/semantics/submittedVersion
    Link to the original source: https://pubs.rsc.org/en/content/articlelanding/2021/cc/d1cc05123g
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Papper original source: Chemical Communications. 57 (90): 11935-11947
    APA: Carbo, Jorge J.; Fernandez, Elena; (2021). Alkoxide activation of tetra-alkoxy diboron reagents in C-B bond formation: a decade of unpredictable reactivity. Chemical Communications, 57(90), 11935-11947. DOI: 10.1039/d1cc05123g
    Article's DOI: 10.1039/d1cc05123g
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2021
    Publication Type: Journal Publications
  • Keywords:

    Catalysis,Ceramics and Composites,Chemistry,Chemistry (Miscellaneous),Chemistry, Multidisciplinary,Electronic, Optical and Magnetic Materials,Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films
    Tertiary
    Metal-free diboration
    Complexes
    Catalyst
    Borylation
    Bis(pinacolato)diboron
    Beta-boration
    Alkynes
    Alcohols
    Additions
    Surfaces, coatings and films
    Química
    Metals and alloys
    Medicina ii
    Medicina i
    Materials chemistry
    Materiais
    Interdisciplinar
    General medicine
    General chemistry
    Farmacia
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Engenharias i
    Electronic, optical and magnetic materials
    Ciências biológicas iii
    Ciências biológicas ii
    Ciências biológicas i
    Ciências ambientais
    Ciências agrárias i
    Chemistry, multidisciplinary
    Chemistry (miscellaneous)
    Chemistry (all)
    Chemistry
    Ceramics and composites
    Catalysis
    Biotecnología
    Biodiversidade
    Astronomia / física
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