Author, as appears in the article.: Carbo, Jorge J.; Fernandez, Elena;

Department: Química Física i Inorgànica

URV's Author/s: Carbó Martin, Jorge Juan / Fernández Gutiérrez, Maria Elena

Keywords: Tertiary Metal-free diboration Complexes Catalyst Borylation Bis(pinacolato)diboron Beta-boration Alkynes Alcohols Additions

Abstract: Any attempt to facilitate a new generation of C-B bonds represents a useful tool in organic synthesis. In addition, if that approach highlights the nucleophilic character of boryl moieties in the absence of transition metal complexes, the challenge to create new reactive platforms becomes an opportunity. We have been deeply involved in the experimental and theoretical validation of C-B bond formation by means of alkoxide activation of tetra-alkoxy diboron reagents and here is presented a convenient guide to understand the concept and the applications.

Thematic Areas: Surfaces, coatings and films Química Metals and alloys Medicina ii Medicina i Materials chemistry Materiais Interdisciplinar General medicine General chemistry Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Electronic, optical and magnetic materials Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Ceramics and composites Catalysis Biotecnología Biodiversidade Astronomia / física

licence for use: https://creativecommons.org/licenses/by/3.0/es/

Author's mail: mariaelena.fernandez@urv.cat j.carbo@urv.cat

Author identifier: 0000-0001-9025-1791 0000-0002-3945-6721

Record's date: 2023-03-06

Papper version: info:eu-repo/semantics/submittedVersion

Link to the original source: https://pubs.rsc.org/en/content/articlelanding/2021/cc/d1cc05123g

Licence document URL: http://repositori.urv.cat/ca/proteccio-de-dades/

Papper original source: Chemical Communications. 57 (90): 11935-11947

APA: Carbo, Jorge J.; Fernandez, Elena; (2021). Alkoxide activation of tetra-alkoxy diboron reagents in C-B bond formation: a decade of unpredictable reactivity. Chemical Communications, 57(90), 11935-11947. DOI: 10.1039/d1cc05123g

Article's DOI: 10.1039/d1cc05123g

Entity: Universitat Rovira i Virgili

Journal publication year: 2021

Publication Type: Journal Publications