Autor según el artículo: Carbo, Jorge J.; Fernandez, Elena;

Departamento: Química Física i Inorgànica

Autor/es de la URV: Carbó Martin, Jorge Juan / Fernández Gutiérrez, Maria Elena

Palabras clave: Tertiary Metal-free diboration Complexes Catalyst Borylation Bis(pinacolato)diboron Beta-boration Alkynes Alcohols Additions

Resumen: Any attempt to facilitate a new generation of C-B bonds represents a useful tool in organic synthesis. In addition, if that approach highlights the nucleophilic character of boryl moieties in the absence of transition metal complexes, the challenge to create new reactive platforms becomes an opportunity. We have been deeply involved in the experimental and theoretical validation of C-B bond formation by means of alkoxide activation of tetra-alkoxy diboron reagents and here is presented a convenient guide to understand the concept and the applications.

Áreas temáticas: Surfaces, coatings and films Química Metals and alloys Medicina ii Medicina i Materials chemistry Materiais Interdisciplinar General medicine General chemistry Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Electronic, optical and magnetic materials Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Ceramics and composites Catalysis Biotecnología Biodiversidade Astronomia / física

Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/

Direcció de correo del autor: mariaelena.fernandez@urv.cat j.carbo@urv.cat

Identificador del autor: 0000-0001-9025-1791 0000-0002-3945-6721

Fecha de alta del registro: 2023-03-06

Versión del articulo depositado: info:eu-repo/semantics/submittedVersion

Enlace a la fuente original: https://pubs.rsc.org/en/content/articlelanding/2021/cc/d1cc05123g

URL Documento de licencia: http://repositori.urv.cat/ca/proteccio-de-dades/

Referencia al articulo segun fuente origial: Chemical Communications. 57 (90): 11935-11947

Referencia de l'ítem segons les normes APA: Carbo, Jorge J.; Fernandez, Elena; (2021). Alkoxide activation of tetra-alkoxy diboron reagents in C-B bond formation: a decade of unpredictable reactivity. Chemical Communications, 57(90), 11935-11947. DOI: 10.1039/d1cc05123g

DOI del artículo: 10.1039/d1cc05123g

Entidad: Universitat Rovira i Virgili

Año de publicación de la revista: 2021

Tipo de publicación: Journal Publications