Articles producció científica> Química Física i Inorgànica

Alkoxide activation of tetra-alkoxy diboron reagents in C-B bond formation: a decade of unpredictable reactivity

  • Datos identificativos

    Identificador: imarina:9231292
    Autores:
    Carbo, Jorge J.Fernandez, Elena
    Resumen:
    Any attempt to facilitate a new generation of C-B bonds represents a useful tool in organic synthesis. In addition, if that approach highlights the nucleophilic character of boryl moieties in the absence of transition metal complexes, the challenge to create new reactive platforms becomes an opportunity. We have been deeply involved in the experimental and theoretical validation of C-B bond formation by means of alkoxide activation of tetra-alkoxy diboron reagents and here is presented a convenient guide to understand the concept and the applications.
  • Otros:

    Autor según el artículo: Carbo, Jorge J.; Fernandez, Elena;
    Departamento: Química Física i Inorgànica
    Autor/es de la URV: Carbó Martin, Jorge Juan / Fernández Gutiérrez, Maria Elena
    Palabras clave: Tertiary Metal-free diboration Complexes Catalyst Borylation Bis(pinacolato)diboron Beta-boration Alkynes Alcohols Additions
    Resumen: Any attempt to facilitate a new generation of C-B bonds represents a useful tool in organic synthesis. In addition, if that approach highlights the nucleophilic character of boryl moieties in the absence of transition metal complexes, the challenge to create new reactive platforms becomes an opportunity. We have been deeply involved in the experimental and theoretical validation of C-B bond formation by means of alkoxide activation of tetra-alkoxy diboron reagents and here is presented a convenient guide to understand the concept and the applications.
    Áreas temáticas: Surfaces, coatings and films Química Metals and alloys Medicina ii Medicina i Materials chemistry Materiais Interdisciplinar General medicine General chemistry Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Electronic, optical and magnetic materials Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Ceramics and composites Catalysis Biotecnología Biodiversidade Astronomia / física
    Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
    Direcció de correo del autor: j.carbo@urv.cat mariaelena.fernandez@urv.cat
    Identificador del autor: 0000-0002-3945-6721 0000-0001-9025-1791
    Fecha de alta del registro: 2024-07-27
    Versión del articulo depositado: info:eu-repo/semantics/submittedVersion
    Enlace a la fuente original: https://pubs.rsc.org/en/content/articlelanding/2021/cc/d1cc05123g
    URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referencia al articulo segun fuente origial: Chemical Communications. 57 (90): 11935-11947
    Referencia de l'ítem segons les normes APA: Carbo, Jorge J.; Fernandez, Elena; (2021). Alkoxide activation of tetra-alkoxy diboron reagents in C-B bond formation: a decade of unpredictable reactivity. Chemical Communications, 57(90), 11935-11947. DOI: 10.1039/d1cc05123g
    DOI del artículo: 10.1039/d1cc05123g
    Entidad: Universitat Rovira i Virgili
    Año de publicación de la revista: 2021
    Tipo de publicación: Journal Publications
  • Palabras clave:

    Catalysis,Ceramics and Composites,Chemistry,Chemistry (Miscellaneous),Chemistry, Multidisciplinary,Electronic, Optical and Magnetic Materials,Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films
    Tertiary
    Metal-free diboration
    Complexes
    Catalyst
    Borylation
    Bis(pinacolato)diboron
    Beta-boration
    Alkynes
    Alcohols
    Additions
    Surfaces, coatings and films
    Química
    Metals and alloys
    Medicina ii
    Medicina i
    Materials chemistry
    Materiais
    Interdisciplinar
    General medicine
    General chemistry
    Farmacia
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Engenharias i
    Electronic, optical and magnetic materials
    Ciências biológicas iii
    Ciências biológicas ii
    Ciências biológicas i
    Ciências ambientais
    Ciências agrárias i
    Chemistry, multidisciplinary
    Chemistry (miscellaneous)
    Chemistry (all)
    Chemistry
    Ceramics and composites
    Catalysis
    Biotecnología
    Biodiversidade
    Astronomia / física
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