Articles producció científicaQuímica Analítica i Química Orgànica

Palladium-catalyzed allylic amination: a powerful tool for the enantioselective synthesis of acyclic nucleoside phosphonates

  • Identification data

    Identifier:  imarina:9297384
    Handle: https://hdl.handle.net/20.500.11797/imarina9297384
    Authors:  Azzouz, M; Soriano, S; Escudero-Casao, M; Matheu, MI; Castillón, S; Díaz, Y
    Abstract:
    Acyclic nucleoside phosphonates have been prepared in a straightforward manner and in high yields by an enantioselective palladium-catalyzed allylic substitution involving nucleic bases as nucleophiles followed by cross-metathesis reaction with diethyl allylphosphonate.

  • Others:

    Link to the original source: https://pubs.rsc.org/en/content/articlehtml/2017/ob/c7ob01478c
    APA: Azzouz, M; Soriano, S; Escudero-Casao, M; Matheu, MI; Castillón, S; Díaz, Y (2017). Palladium-catalyzed allylic amination: a powerful tool for the enantioselective synthesis of acyclic nucleoside phosphonates. Organic & Biomolecular Chemistry, 15(34), 7227-7234. DOI: 10.1039/C7OB01478C
    Paper original source: Organic & Biomolecular Chemistry. 15 (34): 7227-7234
    Article's DOI: 10.1039/C7OB01478C
    Journal publication year: 2017-09-14
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/publishedVersion
    Record's date: 2026-05-09
    URV's Author/s: Castillón Miranda, Sergio / Díaz Giménez, María Yolanda / Matheu Malpartida, María Isabel
    Department: Química Analítica i Química Orgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Journal Publications
    Author, as appears in the article.: Azzouz, M; Soriano, S; Escudero-Casao, M; Matheu, MI; Castillón, S; Díaz, Y
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Thematic Areas: Physical and theoretical chemistry, Organic chemistry, Interdisciplinar, General medicine, Chemistry, organic, Biochemistry, Astronomia / física
    Author's mail: sergio.castillon@urv.cat, sergio.castillon@urv.cat, yolanda.diaz@urv.cat, yolanda.diaz@urv.cat, yolanda.diaz@urv.cat, maribel.matheu@urv.cat, maribel.matheu@urv.cat

  • Keywords:

    Strategy
    Ring-closing metathesis
    Palladium-catalyzed allylic substitution
    Palladium
    Organophosphonates
    Nucleosides
    Heterocycles
    Formal synthesis
    Enantioselective synthesis
    Efficient
    Derivatives
    Cross-metathesis
    Complexes
    Chemistry techniques
    synthetic
    Catalysis
    Carbanucleosides
    Amination
    Alpha
    beta-unsaturated ketones
    Alkenes
    Biochemistry
    Chemistry
    Organic
    Organic Chemistry
    Physical and Theoretical Chemistry
    Interdisciplinar
    General medicine
    Astronomia / física

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