Articles producció científica> Química Analítica i Química Orgànica

Palladium-catalyzed allylic amination: a powerful tool for the enantioselective synthesis of acyclic nucleoside phosphonates

  • Identification data

    Identifier: imarina:9297384
    Authors:
    Azzouz, MariamSoriano, SebastienEscudero-Casao, MargaritaIsabel Matheu, M.Castillon, SergioDiaz, Yolanda
    Abstract:
    Acyclic nucleoside phosphonates have been prepared in a straightforward manner and in high yields by an enantioselective palladium-catalyzed allylic substitution involving nucleic bases as nucleophiles followed by cross-metathesis reaction with diethyl allylphosphonate.
  • Others:

    Author, as appears in the article.: Azzouz, Mariam; Soriano, Sebastien; Escudero-Casao, Margarita; Isabel Matheu, M.; Castillon, Sergio; Diaz, Yolanda;
    Department: Química Analítica i Química Orgànica
    URV's Author/s: Castillón Miranda, Sergio / Díaz Giménez, María Yolanda / Matheu Malpartida, María Isabel
    Keywords: Strategy Ring-closing metathesis Palladium-catalyzed allylic substitution Heterocycles Formal synthesis Enantioselective synthesis Efficient Derivatives Cross-metathesis Complexes Carbanucleosides Alpha,beta-unsaturated ketones
    Abstract: Acyclic nucleoside phosphonates have been prepared in a straightforward manner and in high yields by an enantioselective palladium-catalyzed allylic substitution involving nucleic bases as nucleophiles followed by cross-metathesis reaction with diethyl allylphosphonate.
    Thematic Areas: Química Physical and theoretical chemistry Organic chemistry Odontología Medicina ii Medicina i Materiais Interdisciplinar General medicine Farmacia Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências agrárias i Chemistry, organic Biotecnología Biodiversidade Biochemistry
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Author's mail: yolanda.diaz@urv.cat maribel.matheu@urv.cat sergio.castillon@urv.cat
    Author identifier: 0000-0001-5567-8108 0000-0001-5216-9260 0000-0002-0690-7549
    Record's date: 2024-09-07
    Papper version: info:eu-repo/semantics/publishedVersion
    Link to the original source: https://pubs.rsc.org/en/content/articlehtml/2017/ob/c7ob01478c
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Papper original source: Organic & Biomolecular Chemistry. 15 (34): 7227-7234
    APA: Azzouz, Mariam; Soriano, Sebastien; Escudero-Casao, Margarita; Isabel Matheu, M.; Castillon, Sergio; Diaz, Yolanda; (2017). Palladium-catalyzed allylic amination: a powerful tool for the enantioselective synthesis of acyclic nucleoside phosphonates. Organic & Biomolecular Chemistry, 15(34), 7227-7234. DOI: 10.1039/C7OB01478C
    Article's DOI: 10.1039/C7OB01478C
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2017
    Publication Type: Journal Publications
  • Keywords:

    Biochemistry,Chemistry, Organic,Organic Chemistry,Physical and Theoretical Chemistry
    Strategy
    Ring-closing metathesis
    Palladium-catalyzed allylic substitution
    Heterocycles
    Formal synthesis
    Enantioselective synthesis
    Efficient
    Derivatives
    Cross-metathesis
    Complexes
    Carbanucleosides
    Alpha,beta-unsaturated ketones
    Química
    Physical and theoretical chemistry
    Organic chemistry
    Odontología
    Medicina ii
    Medicina i
    Materiais
    Interdisciplinar
    General medicine
    Farmacia
    Ciências biológicas iii
    Ciências biológicas ii
    Ciências biológicas i
    Ciências agrárias i
    Chemistry, organic
    Biotecnología
    Biodiversidade
    Biochemistry
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