Articles producció científicaQuímica Analítica i Química Orgànica

Role of σ,π-Digold(I) Alkyne Complexes in Reactions of Enynes

  • Identification data

    Identifier:  imarina:9440781
    Handle: https://hdl.handle.net/20.500.11797/imarina9440781
    Authors:  Ferrer, Sofia; Echavarren, Antonio M
    Abstract:
    Gold(I) acetylide and sigma,pi-digold(I) alkyne complexes derived from one prototypical 1,6-enyne and from 7-ethynyl-1,3,5-cycloheptatriene have been prepared and structurally characterized. Their possible role in gold(I)-catalyzed cycloisomerizations has been studied by experiment and by DFT calculations. Gold(I) acetylides are totally unproductive complexes in the absence of Bronsted acids. Similarly, no cyclizations were observed by heating sigma,pi-digold(I) alkyne digold(I) at least up to 130 degrees C. Theoretical studies provide a rationale for the much lower reactivity of digold species in reactions of enynes.

  • Others:

    Link to the original source: https://pubs.acs.org/doi/10.1021/acs.organomet.7b00668
    APA: Ferrer, Sofia; Echavarren, Antonio M (2018). Role of σ,π-Digold(I) Alkyne Complexes in Reactions of Enynes. Organometallics, 37(5), 781-786. DOI: 10.1021/acs.organomet.7b00668
    Paper original source: Organometallics. 37 (5): 781-786
    Article's DOI: 10.1021/acs.organomet.7b00668
    Journal publication year: 2018
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/publishedVersion
    Record's date: 2025-02-18
    URV's Author/s: ECHAVARREN PABLOS, ANTONIO
    Department: Química Analítica i Química Orgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Journal Publications
    Author, as appears in the article.: Ferrer, Sofia; Echavarren, Antonio M
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Thematic Areas: Química, Physical and theoretical chemistry, Organic chemistry, Materiais, Inorganic chemistry, Engenharias ii, Ciências biológicas ii, Ciências agrárias i, Chemistry, organic, Chemistry, inorganic & nuclear, Astronomia / física
    Author's mail: antoniomaria.echavarren@urv.cat

  • Keywords:

    Tris(alkyne
    Terminal alkynes
    Skeletal rearrangement
    Intermolecular 2+2 cycloaddition
    Gold-catalyzed synthesis
    Dual-activation
    Cycloisomerization
    Bronsted acid
    Bis(alkyne) complexes
    Binding
    Chemistry
    Inorganic & Nuclear
    Organic
    Inorganic Chemistry
    Organic Chemistry
    Physical and Theoretical Chemistry
    Química
    Materiais
    Engenharias ii
    Ciências biológicas ii
    Ciências agrárias i
    Astronomia / física

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