Articles producció científicaQuímica Analítica i Química Orgànica

Role of σ,π-Digold(I) Alkyne Complexes in Reactions of Enynes

  • Datos identificativos

    Identificador:  imarina:9440781
    Handle: https://hdl.handle.net/20.500.11797/imarina9440781
    Autores:  Ferrer, Sofia; Echavarren, Antonio M
    Resumen:
    Gold(I) acetylide and sigma,pi-digold(I) alkyne complexes derived from one prototypical 1,6-enyne and from 7-ethynyl-1,3,5-cycloheptatriene have been prepared and structurally characterized. Their possible role in gold(I)-catalyzed cycloisomerizations has been studied by experiment and by DFT calculations. Gold(I) acetylides are totally unproductive complexes in the absence of Bronsted acids. Similarly, no cyclizations were observed by heating sigma,pi-digold(I) alkyne digold(I) at least up to 130 degrees C. Theoretical studies provide a rationale for the much lower reactivity of digold species in reactions of enynes.

  • Otros:

    Enlace a la fuente original: https://pubs.acs.org/doi/10.1021/acs.organomet.7b00668
    Referencia de l'ítem segons les normes APA: Ferrer, Sofia; Echavarren, Antonio M (2018). Role of σ,π-Digold(I) Alkyne Complexes in Reactions of Enynes. Organometallics, 37(5), 781-786. DOI: 10.1021/acs.organomet.7b00668
    Referencia al articulo segun fuente origial: Organometallics. 37 (5): 781-786
    DOI del artículo: 10.1021/acs.organomet.7b00668
    Año de publicación de la revista: 2018
    Entidad: Universitat Rovira i Virgili
    Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
    Fecha de alta del registro: 2025-02-18
    Autor/es de la URV: ECHAVARREN PABLOS, ANTONIO
    Departamento: Química Analítica i Química Orgànica
    URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
    Tipo de publicación: Journal Publications
    Autor según el artículo: Ferrer, Sofia; Echavarren, Antonio M
    Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
    Áreas temáticas: Química, Physical and theoretical chemistry, Organic chemistry, Materiais, Inorganic chemistry, Engenharias ii, Ciências biológicas ii, Ciências agrárias i, Chemistry, organic, Chemistry, inorganic & nuclear, Astronomia / física
    Direcció de correo del autor: antoniomaria.echavarren@urv.cat

  • Palabras clave:

    Tris(alkyne
    Terminal alkynes
    Skeletal rearrangement
    Intermolecular 2+2 cycloaddition
    Gold-catalyzed synthesis
    Dual-activation
    Cycloisomerization
    Bronsted acid
    Bis(alkyne) complexes
    Binding
    Chemistry
    Inorganic & Nuclear
    Organic
    Inorganic Chemistry
    Organic Chemistry
    Physical and Theoretical Chemistry
    Química
    Materiais
    Engenharias ii
    Ciências biológicas ii
    Ciências agrárias i
    Astronomia / física

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