Autor según el artículo: del Rio, Vanessa; Pilar Callao, M; Soledad Larrechi, M
Departamento: Química Analítica i Química Orgànica
Autor/es de la URV: Callao Lasmarias, María Pilar / Larrechi García, Maria Soledad
Palabras clave: @infoAeu @residentesaeu @uroweb Etiqueta «#» Hashtag
Resumen: The evaluation of the temperature effect on the competitiveness between the amine addition and the amidation reaction in a model cure acid-catalysed reaction between the epoxidized methyl oleate (EMO), obtained from high oleic sunflower oil, and aniline is reported. The study was carried out analysing the kinetic profiles of the chemical species involved in the system, which were obtained applying multivariate curve resolution-alternating least squares (MCR-ALS) to the Fourier transform infrared spectra data obtained from the reaction monitoring at two different temperatures (60C and 30C). At both experimental temperatures, two mechanisms were postulated: non-autocatalytic and autocatalytic. The different behaviour was discussed considering not only the influence of the temperature on the amidation reaction kinetic, but also the presence of the homopolymerization of the EMO reagent.
Áreas temáticas: Química Medicina ii Medicina i Materiais Farmacia Ensino Engenharias i Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciência de alimentos Chemistry, analytical Biotecnología Biodiversidade Astronomia / física Analytical chemistry
Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 1687-8760
Direcció de correo del autor: mariapilar.callao@urv.cat
Identificador del autor: 0000-0003-2691-329X
Fecha de alta del registro: 2024-11-16
Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
Enlace a la fuente original: https://www.hindawi.com/journals/ijac/2011/401216/
URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
Referencia al articulo segun fuente origial: International Journal Of Analytical Chemistry. 2011 401216-10
Referencia de l'ítem segons les normes APA: del Rio, Vanessa; Pilar Callao, M; Soledad Larrechi, M (2011). Analysing the Temperature Effect on the Competitiveness of the Amine Addition versus the Amidation Reaction in the Epoxidized Oil/Amine System by MCR-ALS of FTIR Data. International Journal Of Analytical Chemistry, 2011(), 401216-10. DOI: 10.1155/2011/401216
DOI del artículo: 10.1155/2011/401216
Entidad: Universitat Rovira i Virgili
Año de publicación de la revista: 2011
Tipo de publicación: Journal Publications
Repositori URV